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Quasielastic neutron scattering study of pyridinium cation reorientation in thiourea pyridinium nitrate inclusion compound
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10.1063/1.2833961
/content/aip/journal/jcp/128/8/10.1063/1.2833961
http://aip.metastore.ingenta.com/content/aip/journal/jcp/128/8/10.1063/1.2833961
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

The structure of bis-thiourea pyridinium nitrate inclusion compound at (Ref. 11). View along the axis.

Image of FIG. 2.
FIG. 2.

Typical QENS spectra for . The solid line is fitted spectra, the dot line is the resolution function, and the dashed line is quasielstic contribution. The entire fitted spectra are shown in the insets.

Image of FIG. 3.
FIG. 3.

Experimental elastic incoherent structure factor (EISF) of bis-thiourea pyridinium nitrate inclusion compound.

Image of FIG. 4.
FIG. 4.

Experimental (points) and calculated EISF (lines) for various jump models. For details see text.

Image of FIG. 5.
FIG. 5.

The model of the motion of pyridinium cation—reorientation about the axis passing through two opposite atoms of the pyridinium cation by .

Image of FIG. 6.
FIG. 6.

The model of the motion of pyridinium cation—reorientation about the axis joining two opposite bond centers by .

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/content/aip/journal/jcp/128/8/10.1063/1.2833961
2008-02-26
2014-04-18
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Quasielastic neutron scattering study of pyridinium cation reorientation in thiourea pyridinium nitrate inclusion compound
http://aip.metastore.ingenta.com/content/aip/journal/jcp/128/8/10.1063/1.2833961
10.1063/1.2833961
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