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Formation of the diphenyl molecule in the crossed beam reaction of phenyl radicals with benzene
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10.1063/1.2834221
/content/aip/journal/jcp/128/8/10.1063/1.2834221
http://aip.metastore.ingenta.com/content/aip/journal/jcp/128/8/10.1063/1.2834221
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Time-of-flight data of the D5-diphenyl molecule recorded at at selected laboratory angles; open circles represent experimental data, the solid line the fit.

Image of FIG. 2.
FIG. 2.

Upper: Laboratory angular distribution of the D5-diphenyl molecule recorded at . Circles and error bars indicate experimental data, the solid lines the calculated distribution, and CM the center-of-mass angle. Lower: Newton diagram for the reaction of phenyl radicals with D6-benzene. The circle stands for the maximum center-of-mass recoil velocity of the D5-diphenyl product.

Image of FIG. 3.
FIG. 3.

Center-of-mass angular flux distribution (upper) and center-of-mass translational energy flux distribution (lower) for the reaction of phenyl radicals with D6-benzene to form atomic deuterium plus the D5-biphenyl molecule.

Image of FIG. 4.
FIG. 4.

Schematic representation of the reaction mechanism of phenyl radicals with D6-benzene leading to D5-diphenyl plus atomic deuterium (right) via a doublet radical intermediate (center). Carbon, hydrogen, and deuterium atoms are depicted in black, dark blue, and light blue, respectively.

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/content/aip/journal/jcp/128/8/10.1063/1.2834221
2008-02-29
2014-04-23
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Formation of the diphenyl molecule in the crossed beam reaction of phenyl radicals with benzene
http://aip.metastore.ingenta.com/content/aip/journal/jcp/128/8/10.1063/1.2834221
10.1063/1.2834221
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