Index of content:
Volume 129, Issue 18, 14 November 2008
129(2008); http://dx.doi.org/10.1063/1.3009766View Description Hide Description
In this work, we describe the design and first experimental results of a new setup that combines evaporation of liquids in ultrahigh vacuum conditions with in situ high sensitivity thermal characterization of thin films. Organic compounds are deposited from the vapor directly onto a liquid nitrogen cooled substrate, permitting the preparation and characterization of glassyfilms. The substrate consists of a microfabricated, membrane-based nanocalorimeter that permits in situ measurements of heat capacity under ultrafast heating rates (up to ) in the temperature range of 100–300 K. Three glass forming liquids—toluene, methanol, and acetic acid—are characterized. The spikes in heat capacity related to the glass-transition temperature, the fictive temperature and, in some cases, the onset temperature of crystallization are determined for several heating rates.
129(2008); http://dx.doi.org/10.1063/1.3009251View Description Hide Description
Lubrication expressions for the friction coefficients of a spherical particle moving in a fluid between and along two parallel solid walls are explicitly evaluated in the low-Reynolds-number regime. They are used to determine lubrication expression for the particle free motion under an ambient Poiseuille flow. The range of validity and the accuracy of the lubrication approximation are determined by comparing with the corresponding results of the accurate multipole procedure. The results are applicable for thin, wide, and long microchannels, or quasi-two-dimensional systems.