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Photodissociation dynamics of propionyl chloride in the ultraviolet region
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10.1063/1.3012353
/content/aip/journal/jcp/130/1/10.1063/1.3012353
http://aip.metastore.ingenta.com/content/aip/journal/jcp/130/1/10.1063/1.3012353

Figures

Image of FIG. 1.
FIG. 1.

Raw ion images of Cl and fragments from the photodissociation of propionyl chloride at 248.5 [(a) and (b)] and 235 nm [(c) and (d)]. The laser is linearly polarized along the vertical direction in all images.

Image of FIG. 2.
FIG. 2.

Center-of-mass translational energy distributions of the Cl and fragmentation from propionyl chloride at 235 and 248 nm. The open circles represent the experimental data. The solid lines denote the corresponding curve fit of the distributions and the dashed and dotted lines indicate the Gaussian fit of the high-kinetic energy components and the Boltzmann fit of the low-kinetic energy components, respectively. The arrows indicate the maximum kinetic energy available for one-photon dissociation.

Image of FIG. 3.
FIG. 3.

Raw ion images of the CO and 1 levels in the photodissociation of propionyl chloride at 230 nm.

Image of FIG. 4.
FIG. 4.

(upper) REMPI spectra of CO ( and 1) produced in the photodissociation of propionyl chloride near 230 nm. (lower) spectral simulation of the rotational state distributions of CO ( and 1) in the transition.

Image of FIG. 5.
FIG. 5.

Power dependence of (a) the Cl and (b) the CO fragments obtained in the photodissociation of propionyl chloride at 235 and 230 nm, respectively.

Image of FIG. 6.
FIG. 6.

determination by the fit of angular distribution for propionyl chloride at 235 nm. (a) for the Cl channel, and (b) for the channel.

Tables

Generic image for table
Table I.

Total available energies, translational energies, fractions of translational energy release, and anisotropy parameters of the chloride fragments in the photodissociation of propionyl chloride.

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/content/aip/journal/jcp/130/1/10.1063/1.3012353
2009-01-07
2014-04-19
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Photodissociation dynamics of propionyl chloride in the ultraviolet region
http://aip.metastore.ingenta.com/content/aip/journal/jcp/130/1/10.1063/1.3012353
10.1063/1.3012353
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