Jacobi vectors used to describe molecule-molecule collisions.
The effective potentials as functions of for the system for , , and .
Upper panel: Partial-wave resolved and total elastic cross sections for collisions as a function of the collision energy. Lower panel: Inelastic state-to-state cross sections for the system as a function of the collision energy. For clarity, only the final CMSs have been shown.
State-to-state cross sections for collisions at an energy of . The parameters corresponding to the black distributions are adopted in the final production calculations. Upper panel: Convergence with respect to the angular anisotropic terms of the PES. Lower panel: Convergence with respect to the number of points for the radial and angular integrations and the cutoff energy for the basis set.
Upper panel: Vibrational relaxation cross sections as functions of the collision energy for the system. Lower panel: State-to-state cross sections at a collision energy of .
Rate coefficient for the vibrational relaxation of in collisions with as a function of the temperature. Results obtained using the BMKP and BMKPE PESs are compared with the experimental results of Audibert et al. (Ref. 46).
Elastic and inelastic cross sections as functions of the collision energy. Upper panel: Elastic cross sections for collisions. Middle panel: Elastic and inelastic cross sections for collisions. Lower panel: Elastic and inelastic cross sections for collisions.
Elastic cross section for collisions as a function of the incident collision energy. The experimental results of Bauer et al. (Ref. 47) and theoretical results of Lee et al. (Ref. 27) are also shown.
State-to-state cross sections for rotational excitation in collisions as functions of the collision energy. The results of Otto et al. (Ref. 43) are included for comparison.
Rate coefficient as a function of the temperature for collisions. The TDWP results of Otto et al. (Ref. 43) and experimental results of Maté et al. (Ref. 26) are also included for comparison. The TDWP results are almost identical to the present results for .
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