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Polarization labeling spectroscopy of highly excited and states in NaLi
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10.1063/1.3095678
/content/aip/journal/jcp/130/12/10.1063/1.3095678
http://aip.metastore.ingenta.com/content/aip/journal/jcp/130/12/10.1063/1.3095678

Figures

Image of FIG. 1.
FIG. 1.

Distribution of the experimental data in the field of vibrational and rotational quantum numbers of the (a) , (b) , and (c) states of NaLi observed in the present experiment.

Image of FIG. 2.
FIG. 2.

The pointwise IPA potential curves of the state constructed using two different theoretical potentials as a starting point: potential of the as calculated by Petsalakis et al. (Ref. 10) (open circles and dashed line) and of the state calculated by Mabrouk and Berriche (Ref. 11) (crosses and solid line). The arrows show limits of the region of reliability of the experimental potential.

Image of FIG. 3.
FIG. 3.

Comparison of the experimental potential curves for higher excited electronic states of NaLi from this and our previous work (Refs. 8 and 9) with calculations of Mabrouk and Berriche (Ref. 11). Points correspond to experimental RKR or IPA potentials (full circles for states, open squares for states) and lines to theoretical curves (solid for and dashed for ).

Image of FIG. 4.
FIG. 4.

Comparison of the experimental potential curves with theoretical predictions of Petsalakis et al. (Ref. 10) presented as in Fig. 3.

Tables

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Table I.

Observed transitions in the molecule excited by the probe (labeling) lasers.

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Table II.

Dunham coefficients (in ) for the and states of determined in the present work. The numbers in parentheses correspond to one standard deviation in units of the last digit and rms stands for the root mean square deviation of the fit.

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Table III.

Rotationless RKR potential energy curve for the state of NaLi.

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Table IV.

The IPA potential curve of the investigated state of NaLi obtained with two different theoretical potentials used as a starting point: of the state (Ref. 11) and of the state (Ref. 10) .

Generic image for table
Table V.

Rotationless RKR potential energy curve for the state of NaLi.

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/content/aip/journal/jcp/130/12/10.1063/1.3095678
2009-03-25
2014-04-17
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Polarization labeling spectroscopy of highly excited Π1 and Σ1+ states in NaLi
http://aip.metastore.ingenta.com/content/aip/journal/jcp/130/12/10.1063/1.3095678
10.1063/1.3095678
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