1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
General theory of excitation energy transfer in donor-mediator-acceptor systems
Rent:
Rent this article for
USD
10.1063/1.3117622
/content/aip/journal/jcp/130/15/10.1063/1.3117622
http://aip.metastore.ingenta.com/content/aip/journal/jcp/130/15/10.1063/1.3117622
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

The model of EET from the electronically excited state of the donor molecule to the state of the acceptor molecule via the state of the mediator molecule: Since the state is the nonequilibrium state of the state of the donor molecule, this model of EET consists of the four states of the three molecules D-M-A.

Image of FIG. 2.
FIG. 2.

The diagrams of the time correlation functions by (a) second-order perturbation, (b) third-order perturbation, and (c) fourth-order perturbation.

Image of FIG. 3.
FIG. 3.

The scheme of sequential EET process in D-M-A system which includes the direct transition from to states.

Image of FIG. 4.
FIG. 4.

Flow chart of formulas obtained in this article.

Image of FIG. 5.
FIG. 5.

Plot of function for , 5, and 20.

Image of FIG. 6.
FIG. 6.

A model system of three transition dipole moments: The solid arrows express the transition dipole moments. The donor and the acceptor are located on the axis. The mediator is located on the axis. is the distance between the donor and the acceptor. is the distance between the donor and the mediator.

Image of FIG. 7.
FIG. 7.

Rate of EET of the superexchange mechanism by the distance dependence between the donor and the mediator: The curves express the total rate of EET , the term of direct transition , the term of interference effect , and the term of indirect transition .

Image of FIG. 8.
FIG. 8.

Rate of EET as a function of where : The curves express the total rate of EET , the term of direct transition , the term of interference effect , the term of indirect transition for superexchange mechanism, and the rate of EET for sequential mechanism.

Image of FIG. 9.
FIG. 9.

Rate of EET as a function of where : The curves express the total rate of EET , the term of direct transition , the term of interference effect , the term of indirect transition for superexchange mechanism, and the rate of EET for sequential mechanism.

Loading

Article metrics loading...

/content/aip/journal/jcp/130/15/10.1063/1.3117622
2009-04-16
2014-04-21
Loading

Full text loading...

This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: General theory of excitation energy transfer in donor-mediator-acceptor systems
http://aip.metastore.ingenta.com/content/aip/journal/jcp/130/15/10.1063/1.3117622
10.1063/1.3117622
SEARCH_EXPAND_ITEM