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Vibrational energy transfer in collisions
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10.1063/1.3132588
/content/aip/journal/jcp/130/19/10.1063/1.3132588
http://aip.metastore.ingenta.com/content/aip/journal/jcp/130/19/10.1063/1.3132588

Figures

Image of FIG. 1.
FIG. 1.

Velocity averaged resonance function as a function of energy mismatch for (isotropic polarizability–isotropic polarizability interaction), (isotropic polarizability–anisotropic polarizability interaction plus anisotropic polarizability–isotropic polarizability interaction), and (anisotropic polarizability–anisotropic polarizability interaction).

Image of FIG. 2.
FIG. 2.

Probability per collision as a function of temperature for the transfer of one quantum of vibrational ET from to for the three dispersion interactions.

Image of FIG. 3.
FIG. 3.

Probability per collision as a function of temperature for the transfer of one quantum of vibrational ET from to for the three dispersion interactions.

Image of FIG. 4.
FIG. 4.

Calculated rate coefficient as a function of vibrational quantum number for the transfer of one quantum of vibrational ET from to for the three dispersion interactions (solid line). The experimental rate coefficients are for the disappearance of upon impact with . Kalogerakis (Ref. 1 ), stars; Ahn (Ref. 2 ), diamonds; Park and Slanger (Ref. 3 ), circle; Klatt (Ref. 5 ), square; and Watanabe (Ref. 37 ), crosses. The dashed line represents the calculation of Hernández (Ref. 13 ).

Tables

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Table I.

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/content/aip/journal/jcp/130/19/10.1063/1.3132588
2009-05-20
2014-04-19
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Vibrational energy transfer in O2(v=2–8)–O2(v=0) collisions
http://aip.metastore.ingenta.com/content/aip/journal/jcp/130/19/10.1063/1.3132588
10.1063/1.3132588
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