1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
A new method for determining absorption cross sections out of initially excited vibrational states
Rent:
Rent this article for
USD
10.1063/1.3067923
/content/aip/journal/jcp/130/5/10.1063/1.3067923
http://aip.metastore.ingenta.com/content/aip/journal/jcp/130/5/10.1063/1.3067923

Figures

Image of FIG. 1.
FIG. 1.

Schematics of the concepts for (a) ionization-loss stimulated Raman spectroscopy, where resonant two-photon ionization of the molecular parent, follows the depletion of ground state reactant species as a result of stimulated Raman excitation and (b) vibrationally mediated photodissociation, where pre-excited molecules are dissociated and the ensuing H photofragments are probed by resonantly enhanced multiphoton ionization.

Image of FIG. 2.
FIG. 2.

Methylamine vibrational spectra: (a) H action spectrum obtained via 243.135 nm dissociation of vibrationally excited molecules and (b) ionization-loss stimulated Raman spectrum exhibiting the depletion of parent molecule ionization signal due to vibrational pre-excitation.

Tables

Generic image for table
Table I.

The excited vibrational modes of methylamine, fraction of excited molecules, enhancement factors, partial cross sections for the 243.135 nm H dissociation out of different initially prepared vibrational states and for excitation of vibrationless ground state molecules at the corresponding combined energies.

Loading

Article metrics loading...

/content/aip/journal/jcp/130/5/10.1063/1.3067923
2009-02-02
2014-04-17
Loading

Full text loading...

This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: A new method for determining absorption cross sections out of initially excited vibrational states
http://aip.metastore.ingenta.com/content/aip/journal/jcp/130/5/10.1063/1.3067923
10.1063/1.3067923
SEARCH_EXPAND_ITEM