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Structural response of a highly viscous aluminoborosilicate melt to isotropic and anisotropic compressions
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10.1063/1.3223282
/content/aip/journal/jcp/131/10/10.1063/1.3223282
http://aip.metastore.ingenta.com/content/aip/journal/jcp/131/10/10.1063/1.3223282

Figures

Image of FIG. 1.
FIG. 1.

Density and fraction of tetrahedrally coordinated boron of isostatically compressed E-glass samples. The line indicates best linear fit through the density data.

Image of FIG. 2.
FIG. 2.

Birefringence of uniaxially compressed E-glass samples. Line indicates best linear fit through the data. The inset shows the specific birefringence as a function of viscosity for different E-glasses. Fiber data (Ref. 28) (see Table I for composition).

Image of FIG. 3.
FIG. 3.

MAS NMR spectra for isostatically compressed E-glass samples (14.1 T), normalized to height of peak.

Image of FIG. 4.
FIG. 4.

MAS NMR spectra for isostatically compressed E-glass samples (18.8 T), normalized to height of peak. Spectra are overlaid to highlight increases in and with pressure, which increases progressively from lowest (0.1 MPa) to uppermost (500 MPa) curve. The inset has vertical .

Image of FIG. 5.
FIG. 5.

MAS spectra for isostatically compressed E-glass samples (14.1 T). Data only for 0.1 MPa (dashed line) and 500 MPa (solid line) are plotted for clarity; 300 MPa glass spectrum would plot between these two curves.

Image of FIG. 6.
FIG. 6.

MAS spectra for isostatically compressed E-glass samples (9.4 T). Data only for 0.1 MPa (dashed line) and 500 MPa (solid line) are plotted for clarity.

Image of FIG. 7.
FIG. 7.

Static spectra on cubes of uniaxially compressed E-glass (142 MPa, 9.4 T), with the orientation of the compression direction relative to the external magnetic field as labeled. (a) ; (b) ; (c) ; (d) .

Tables

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Table I.

Composition of glasses compared in this study, in mol %.

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Table II.

Birefringence data for uniaxially compressed E-glass.

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Table III.

Run conditions, density, and structural data for isostatically compressed E-glass.

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Table IV.

Comparison of effects of pressure on speciation in several glass compositions. Data for maximum pressures only are shown; see Table I for compositions.

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/content/aip/journal/jcp/131/10/10.1063/1.3223282
2009-09-10
2014-04-18
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Structural response of a highly viscous aluminoborosilicate melt to isotropic and anisotropic compressions
http://aip.metastore.ingenta.com/content/aip/journal/jcp/131/10/10.1063/1.3223282
10.1063/1.3223282
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