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Orientational bonding model for temperature dependent micellization and solubility of diblock surfactants
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10.1063/1.3227905
/content/aip/journal/jcp/131/11/10.1063/1.3227905
http://aip.metastore.ingenta.com/content/aip/journal/jcp/131/11/10.1063/1.3227905
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Cmc vs inverse temperature for surfactants in a system of size with (triangles), (circles), and (squares). Solid line is for the same system without orientational bonding (equivalent to ).

Image of FIG. 2.
FIG. 2.

Cmc of (diamonds), (triangles), (circles), and (squares) surfactants in a system size with . Error bars represent statistical uncertainty at the 95% confidence interval for the system, and the uncertainty in other systems is smaller than the symbol size. Solid lines are the same surfactants without orientational bonding.

Image of FIG. 3.
FIG. 3.

A snapshot showing three micelles in a system of size at . monomers are shown at reduced size for visual clarity.

Image of FIG. 4.
FIG. 4.

Phase diagrams (temperature vs volume fraction of lattice occupied by surfactant) for (triangles), (circles), and (squares) systems with and .

Image of FIG. 5.
FIG. 5.

The limit of solubility for , , and surfactants (symbols are the same as for Fig. 4) with and . Error bars represent statistical uncertainty at the 95% confidence interval for the system, and the uncertainty in other systems is smaller than the symbol size. Solid lines are for the same surfactants without orientational bonding.

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/content/aip/journal/jcp/131/11/10.1063/1.3227905
2009-09-15
2014-04-19
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Orientational bonding model for temperature dependent micellization and solubility of diblock surfactants
http://aip.metastore.ingenta.com/content/aip/journal/jcp/131/11/10.1063/1.3227905
10.1063/1.3227905
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