• journal/journal.article
• aip/jcp
• /content/aip/journal/jcp/131/12/10.1063/1.3224124
• jcp.aip.org
1887
No data available.
No metrics data to plot.
The attempt to plot a graph for these metrics has failed.
Metal clusters with hidden ground states: Melting and structural transitions in , , and
USD
10.1063/1.3224124
View Affiliations Hide Affiliations
Affiliations:
1 Department of Chemistry, Indiana University, 800 East Kirkwood Ave., Bloomington, Indiana 47405, USA
a) Electronic mail: mfj@indiana.edu.
J. Chem. Phys. 131, 124305 (2009)
/content/aip/journal/jcp/131/12/10.1063/1.3224124
http://aip.metastore.ingenta.com/content/aip/journal/jcp/131/12/10.1063/1.3224124

## Figures

FIG. 1.

Heat capacities measured as a function of temperature for , , and . The filled black squares are the measured values. The heat capacities are plotted relative to the classical value , where and is the Boltzmann constant. The open blue circles are a fit obtained using a three-state model using (see text). The solid blue lines show heat capacities obtained from the fit with . The lines at the bottom of each plot show the relative abundances of the low energy structure (green), high energy structure (purple), and liquid (red) as a function of temperature (using the scale on the right hand axes).

FIG. 2.

Heat capacities recorded for after annealing to 523 and 773 K (filled black squares). The heat capacities are plotted in units of , where and is the Boltzmann constant. The heat capacities for unannealed are included for comparison. The blue lines are fits to the experimental date values using two- and three-state models with (see text).

## Tables

Table I.

Parameters derived for the structural transitions and melting transitions for , , and by fitting the measured heat capacities with a three-state model (see text).

/content/aip/journal/jcp/131/12/10.1063/1.3224124
2009-09-23
2014-04-18

Article
content/aip/journal/jcp
Journal
5
3

### Most cited this month

More Less
This is a required field