No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.
Molecular rotor dynamics influenced by the elastic modulus of polyethylene nanocomposites
3.A. J. Peacock, Handbook of Polyethylene (Marcel Dekker, New York, 2000).
4.D. Passeri, A. Bettucci, A. Biagioni, M. Rossi, A. Alippi, M. Lucci, I. Davoli, and S. Berezina, Rev. Sci. Instrum. 79, 066105 (2008).
17.G. Ponterini and M. Caselli, Ber. Bunsenges. Phys. Chem 96, 564 (1992).
22.J. R. Lakowicz, Principles of Fluorescence Spectroscopy (Springer, New York, 2006).
24.J. T. Edward, J. Chem. Educ. 47, 261 (1970).
Article metrics loading...
We observed that the excited-state twisting motion of -diethyloxacarbocyanine in polymernanocomposites (PNCs) depends strongly on the elastic modulus of medium. PNCs consist of low density polyethylene dispersed with surface-functionalized nanodiamonds with various alkyl groups. The mechanical properties of the PNCs were measured by a nanoindentation method, and the photoisomerization processes of the cyanine dye doped in the composites were investigated by time-resolved fluorescence spectroscopy. It was found that the molecular rotor dynamics in rigid media should be quantitatively describable by the elastic modulus of polymer.
Full text loading...
Most read this month