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/content/aip/journal/jcp/131/22/10.1063/1.3267729
1.
1.S. C. Glotzer and M. J. Solomon, Nature Mater. 6, 557 (2007).
http://dx.doi.org/10.1038/nmat1949
2.
2.J. N. Israelachvili, D. J. Mitchell, and B. W. Ninham, J. Chem. Soc., Faraday Trans. 2 72, 1525 (1976).
http://dx.doi.org/10.1039/f29767201525
3.
3.S. N. Fejer and D. J. Wales, Phys. Rev. Lett. 99, 086106 (2007).
http://dx.doi.org/10.1103/PhysRevLett.99.086106
4.
4.T. Chen, Z. L. Zhang, and S. C. Glotzer, Langmuir 23, 6598 (2007).
http://dx.doi.org/10.1021/la063755d
5.
5.S. C. Glotzer, M. J. Solomon, and N. A. Kotov, AIChE J. 50, 2978 (2004).
http://dx.doi.org/10.1002/aic.10413
6.
6.J. Y. Lee, A. C. Balazs, R. B. Thompson, and R. M. Hill, Macromolecules 37, 3536 (2004).
http://dx.doi.org/10.1021/ma035542q
7.
7.J. Dobnikar, J. Fornleitner, and G. Kahl, J. Phys.: Condens. Matter 20, 494220 (2008).
http://dx.doi.org/10.1088/0953-8984/20/49/494220
8.
8.J. Fornleitner and G. Kahl, EPL 82, 18001 (2008).
http://dx.doi.org/10.1209/0295-5075/82/18001
9.
9.J. Fornleitner, F. Lo Verso, G. Kahl, and C. N. Likos, Soft Matter 4, 480 (2008).
http://dx.doi.org/10.1039/b717205b
10.
10.J. Fornleitner, F. Lo Verso, G. Kahl, and C. N. Likos, Langmuir 25, 7836 (2009).
http://dx.doi.org/10.1021/la900421v
11.
11.M. A. Glaser, G. M. Grason, R. D. Kamien, A. Kosmrlj, C. D. Santangelo, and P. Ziherl, EPL 78, 46004 (2007).
http://dx.doi.org/10.1209/0295-5075/78/46004
12.
12.G. J. Pauschenwein and G. Kahl, J. Chem. Phys. 129, 174107 (2008).
http://dx.doi.org/10.1063/1.3006065
13.
13.G. J. Pauschenwein and G. Kahl, Soft Matter 4, 1396 (2008).
http://dx.doi.org/10.1039/b806147e
14.
14.H. M. Shin, G. M. Grason, and C. D. Santangelo, Soft Matter 5, 3629 (2009).
http://dx.doi.org/10.1039/b904103f
15.
15.C. N. Likos, N. Hoffman, H. Lwen, and A. Loius, J. Phys.: Condens. Matter 14, 7681 (2002).
http://dx.doi.org/10.1088/0953-8984/14/33/309
16.
16.B. Mladek, D. Gottwald, G. Kahl, M. Newmann, and C. N. Likos, Phys. Rev. Lett. 96, 045701 (2006).
http://dx.doi.org/10.1103/PhysRevLett.96.045701
17.
17.G. Malescio and G. Pellicane, Nature Mater. 2, 93 (2003).
18.
18.R. P. Sear, S. W. Chung, G. Markovich, W. M. Gelbart, and J. R. Heath, Phys. Rev. E 59, R6255 (1999).
http://dx.doi.org/10.1103/PhysRevE.59.R6255
19.
19.R. P. Sear and W. M. Gelbart, J. Chem. Phys. 110, 4582 (1999).
http://dx.doi.org/10.1063/1.478338
20.
20.J. S. Shay, S. R. Raghavan, and S. A. Khan, J. Rheol. 45, 913 (2001).
http://dx.doi.org/10.1122/1.1378030
21.
21.A. D. Dinsmore, V. Prasad, I. Y. Wong, and D. A. Weitz, Phys. Rev. Lett. 96, 185502 (2006).
http://dx.doi.org/10.1103/PhysRevLett.96.185502
22.
22.D. Bedrov, G. D. Smith, and L. W. Li, Langmuir 21, 5251 (2005).
http://dx.doi.org/10.1021/la0504816
23.
23.J. B. Hooper, D. Bedrov, and G. D. Smith, Langmuir 24, 4550 (2008).
http://dx.doi.org/10.1021/la703057y
24.
24.P. Akcora, H. Liu, S. K. Kumar, J. Moll, Y. Li, B. C. Benicewicz, L. S. Schadler, D. Acehan, A. Z. Panagiotopoulos, V. Pryamitsyn, V. Ganesan, J. Ilavsky, P. Thiyagarajan, R. H. Colby, and J. F. Douglas, Nature Mater. 8, 354 (2009).
http://dx.doi.org/10.1038/nmat2404
25.
25.E. B. Zhulina, M. Adam, I. LaRue, S. S. Sheiko, and M. Rubinstein, Macromolecules 38, 5330 (2005).
http://dx.doi.org/10.1021/ma048102n
26.
26.We note that this form is a pure mean-field expression, whereas the other scaling expressions used include phenomenological corrections for the fluctuation/blob picture. This inconsistency is expected to only marginally modify the phase diagrams presented.
27.
27.X. Wang, V. J. Foltz, M. Rackaitis, and G. G. A. Bohm, Polymer 49, 5683 (2008).
http://dx.doi.org/10.1016/j.polymer.2008.10.019
28.
28.The in the theoretical model represents the energy gained on contact between the particles. Explicitly, it is related, but not identical, to the used in simulations.
29.
29.G. Orkoulas and A. Z. Panagiotopoulos, J. Chem. Phys. 101, 1452 (1994).
http://dx.doi.org/10.1063/1.467770
30.
30.A. Bhattacharyay and A. Troisi, Chem. Phys. Lett. 458, 210 (2008).
http://dx.doi.org/10.1016/j.cplett.2008.04.052
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/content/aip/journal/jcp/131/22/10.1063/1.3267729
2009-12-09
2016-12-10

Abstract

Recent experimental results demonstrated that polymer grafted nanoparticles in solvents display self-assembly behavior similar to the microphase separation of block copolymers and other amphiphiles. We present a mean-fieldtheory and complementary computer simulations to shed light on the parametric underpinnings of the experimental observations. Our theory suggests that such self-assembledstructures occur most readily when the nanoparticle size is comparable to the radius of gyration of the polymer brush chains. Much smaller particle sizes are predicted to yield uniform particle dispersions, while larger particles are expected to agglomerate due to phase separation from the solvent. Selected aspects of our theoretical predictions are corroborated by computer simulations.

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