1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Solvation and microscopic properties of ionic liquid/acetonitrile mixtures probed by high-pressure infrared spectroscopy
Rent:
Rent this article for
USD
10.1063/1.3273206
/content/aip/journal/jcp/131/23/10.1063/1.3273206
http://aip.metastore.ingenta.com/content/aip/journal/jcp/131/23/10.1063/1.3273206

Figures

Image of FIG. 1.
FIG. 1.

IR spectra of pure (a) , (b) , and (c) obtained under ambient pressure.

Image of FIG. 2.
FIG. 2.

IR spectra of (a) , (b) , (c) , (d) , and (e) . The mole fractions of ionic liquids are (a) 0.07, (b) 0.09, (c) 0.08, (d) 0.04, and (e) 0.06.

Image of FIG. 3.
FIG. 3.

IR spectra of a mixture (mole fraction of : approximately 0.08) obtained under ambient pressure (curve a) and at 0.3 (curve b), 0.9 (curve c), 1.5 (curve d), 1.9 (curve e), 2.3 (curve f), and 2.5 GPa (curve g).

Image of FIG. 4.
FIG. 4.

IR spectra of a mixture having mole fraction of equal to 0.09 obtained under ambient pressure (curve a) and at 0.3 (curve b), 0.9 (curve c), 1.5 (curve d), 1.9 (curve e), 2.3 (curve f), and 2.5 GPa (curve g).

Image of FIG. 5.
FIG. 5.

IR spectra of a mixture having mole fraction of equal to 0.07 obtained under ambient pressure (curve a) and at 0.3 (curve b), 0.9 (curve c), 1.5 (curve d), 1.9 (curve e), 2.3 (curve f), and 2.5 GPa (curve g).

Image of FIG. 6.
FIG. 6.

Optimized structures of -acetonitrile [(a) and (b)] and -methanol [(c) and (d)].

Tables

Generic image for table
Table I.

Calculated total interaction energies (kcal/mol).

Loading

Article metrics loading...

/content/aip/journal/jcp/131/23/10.1063/1.3273206
2009-12-17
2014-04-18
Loading

Full text loading...

This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Solvation and microscopic properties of ionic liquid/acetonitrile mixtures probed by high-pressure infrared spectroscopy
http://aip.metastore.ingenta.com/content/aip/journal/jcp/131/23/10.1063/1.3273206
10.1063/1.3273206
SEARCH_EXPAND_ITEM