Skip to main content

News about Scitation

In December 2016 Scitation will launch with a new design, enhanced navigation and a much improved user experience.

To ensure a smooth transition, from today, we are temporarily stopping new account registration and single article purchases. If you already have an account you can continue to use the site as normal.

For help or more information please visit our FAQs.

banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.
/content/aip/journal/jcp/132/17/10.1063/1.3428395
1.
1.G. Gouy, J. Phys. 9, 457 (1910);
1.D. L. Chapman, Philos. Mag. 25, 475 (1913);
1.O. Stern, Z. Elektrochem. Angew. Phys. Chem. 30, 508 (1924);
1.C. Gavach, P. Seta, and B. d'Epenoux, J. Electroanal. Chem. 83, 225 (1977).
http://dx.doi.org/10.1016/S0022-0728(77)80168-X
2.
2.G. Luo, S. Malkova, J. Yoon, D. G. Schultz, B. Lin, M. Meron, I. Benjamin, P. Vanysek, and M. L. Schlossman, J. Electroanal. Chem. 593, 142 (2006);
http://dx.doi.org/10.1016/j.jelechem.2006.03.051
2.G. Luo, S. Malkova, J. Yoon, D. G. Schultz, B. Lin, M. Meron, I. Benjamin, P. Vanysek, and M. L. Schlossman,Science 311, 216 (2006).
http://dx.doi.org/10.1126/science.1120392
3.
3.E. R. A. Lima, D. Horinek, R. R. Netz, E. C. Biscaia, F. W. Tavares, W. Kunz, and M. Bostrom, J. Phys. Chem. B 112, 1580 (2008).
http://dx.doi.org/10.1021/jp7098174
4.
4.A. Y. Grosberg, T. T. Nguyen, and B. I. Shklovskii, Rev. Mod. Phys. 74, 329 (2002).
http://dx.doi.org/10.1103/RevModPhys.74.329
5.
5.D. J. Fermín, H. D. Duong, Z. Ding, P. -F. Brevet, and H. H. Girault, Phys. Chem. Chem. Phys. 1, 1461 (1999).
http://dx.doi.org/10.1039/a900142e
6.
6.F. M. Raymond and T. Shedlovsky, J. Am. Chem. Soc. 71, 1496 (1949).
7.
7.W. Schmickler, Interfacial Electrochemistry (Oxford University Press, Oxford, 1996).
8.
8.M. L. Schlossman, D. Synal, Y. Guan, M. Meron, G. Shea-McCarthy, Z. Huang, A. Acero, S. M. Williams, S. A. Rice, and P. J. Viccaro, Rev. Sci. Instrum. 68, 4372 (1997).
http://dx.doi.org/10.1063/1.1148399
9.
9.Z. Zhang, D. M. Mitrinovic, S. M. Williams, Z. Huang, and M. L. Schlossman, J. Chem. Phys. 110, 7421 (1999).
http://dx.doi.org/10.1063/1.478644
10.
10.Gibbs energies of transfer: (57 kJ/mol), (53 kJ/mol), (−56 kJ/mol), (−72.5 kJ/mol), last two measured by partitioning via UV-visible spectroscopy and mass spectroscopy.
11.
11.A. G. Volkov and D. W. Deamer, Liquid-Liquid Interfaces: Theory and Methods (CRC, Boca Raton, 1996).
12.
12.Y. Marcus, Chem. Rev. (Washington, D.C.) 88, 1475 (1988).
http://dx.doi.org/10.1021/cr00090a003
13.
13.C. Zheng and P. Vanysek (unpublished).
14.
14.D. Horinek and R. R. Netz, Phys. Rev. Lett. 99, 226104 (2007).
http://dx.doi.org/10.1103/PhysRevLett.99.226104
15.
15.L. I. Daikhin, A. A. Kornyshev, and M. Urbakh, J. Electroanal. Chem. 500, 461 (2001).
http://dx.doi.org/10.1016/S0022-0728(00)00484-8
16.
16.I. Benjamin, J. Chem. Phys. 129, 074508 (2008).
http://dx.doi.org/10.1063/1.2970083
17.
17.C. D. Wick and L. X. Dang, J. Phys. Chem. C 112, 647 (2008).
http://dx.doi.org/10.1021/jp076608c
18.
18.S. A. Safran, Statistical Thermodynamics of Surfaces, Interfaces, and Membranes (Addison-Wesley, Reading, MA, 1994).
19.
19.G. Luo, S. Malkova, S. V. Pingali, D. G. Schultz, B. Lin, M. Meron, I. Benjamin, P. Vanysek, and M. L. Schlossman, J. Phys. Chem. B 110, 4527 (2006).
http://dx.doi.org/10.1021/jp057103u
20.
20.F. Leveiller, D. Jacquemain, M. Lahav, L. Leiserowitz, M. Deutsch, K. Kjaer, and J. Als-Nielsen, Science 252, 1532 (1991).
http://dx.doi.org/10.1126/science.252.5012.1532
21.
21.B. Winter and M. Faubel, Chem. Rev. (Washington, D.C.) 106, 1176 (2006);
http://dx.doi.org/10.1021/cr040381p
21.L. X. Dang, J. Phys. Chem. B 106, 10388 (2002).
http://dx.doi.org/10.1021/jp021871t
22.
22.M. J. Frisch, G. W. Trucks, H. B. Schlegel et al., GAUSSIAN 03, Gaussian Inc., Pittsburgh, PA, 2003;
22. geometry optimized at level with tightest constraints on convergence (, ). Resultant geometry agreed closely with crystal structure. Polarizability tensor calculated from optimized structure at the same level of theory.
23.
23.I. Borukhov, D. Andelman, and H. Orland, Phys. Rev. Lett. 79, 435 (1997).
http://dx.doi.org/10.1103/PhysRevLett.79.435
http://aip.metastore.ingenta.com/content/aip/journal/jcp/132/17/10.1063/1.3428395
Loading
/content/aip/journal/jcp/132/17/10.1063/1.3428395
Loading

Data & Media loading...

Loading

Article metrics loading...

/content/aip/journal/jcp/132/17/10.1063/1.3428395
2010-05-07
2016-12-07

Abstract

X-rayreflectivity studies demonstrate the condensation of a monovalent ion at the electrified interface between electrolyte solutions of water and 1,2-dichloroethane. Predictions of the ion distributions by standard Poisson–Boltzmann (Gouy–Chapman) theory are inconsistent with these data at higher applied interfacial electric potentials. Calculations from a Poisson–Boltzmann equation that incorporates a nonmonotonic ion-specific potential of mean force are in good agreement with the data.

Loading

Full text loading...

/deliver/fulltext/aip/journal/jcp/132/17/1.3428395.html;jsessionid=YlSHqFkGmCm5dBMU-qDplB4e.x-aip-live-02?itemId=/content/aip/journal/jcp/132/17/10.1063/1.3428395&mimeType=html&fmt=ahah&containerItemId=content/aip/journal/jcp
true
true

Access Key

  • FFree Content
  • OAOpen Access Content
  • SSubscribed Content
  • TFree Trial Content
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
/content/realmedia?fmt=ahah&adPositionList=
&advertTargetUrl=//oascentral.aip.org/RealMedia/ads/&sitePageValue=jcp.aip.org/132/17/10.1063/1.3428395&pageURL=http://scitation.aip.org/content/aip/journal/jcp/132/17/10.1063/1.3428395'
Right1,Right2,Right3,