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Enabling enelike reactions on through tuning organic molecular structures
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10.1063/1.3407442
/content/aip/journal/jcp/132/21/10.1063/1.3407442
http://aip.metastore.ingenta.com/content/aip/journal/jcp/132/21/10.1063/1.3407442

Figures

Image of FIG. 1.
FIG. 1.

HREELS spectra as a function of chloroacetonitrile exposure at 110 K [(a) 0.015 L, (b) 0.25 L, and (c) 8 L] and for the saturated chemisorption monolayer obtained after annealing the multilayer chloroacetonitrile-covered sample to 300 K (d) on the surface. , specular geometry.

Image of FIG. 2.
FIG. 2.

Schematic diagram for the adsorption of chloroacetonitrile on .

Image of FIG. 3.
FIG. 3.

Cl 2p XPS spectra for physisorbed and chemisorbed chloroacetonitrile (obtained by annealing the physisorbed multilayer-covered surface to 300 K) on .

Image of FIG. 4.
FIG. 4.

N 1s XPS spectra for physisorbed and chemisorbed chloroacetonitrile (obtained by annealing the physisorbed multilayer-covered surface to 300 K) on .

Image of FIG. 5.
FIG. 5.

C 1s XPS spectra for physisorbed and chemisorbed chloroacetonitrile (obtained by annealing the physisorbed multilayer-covered surface to 300 K) on .

Image of FIG. 6.
FIG. 6.

HREELS spectra of the surface obtained after exposing propargyl chloride to at 110 K: 0.4 L (a); 1.6 L (b); 3.2 L (c); and annealing (c) to 200 K to desorb physisorbed molecules (d). , specular geometry.

Image of FIG. 7.
FIG. 7.

Cl 2p XPS spectra for physisorbed and chemisorbed propargyl chloride (obtained by annealing the physisorbed multilayer-covered surface to 200 K) on .

Image of FIG. 8.
FIG. 8.

C 1s XPS spectra of physisorbed and chemisorbed propargyl chloride (obtained by annealing the physisorbed multilayer-covered surface to 200 K) on .

Image of FIG. 9.
FIG. 9.

Schematic diagram for the adsorption of propargyl chloride on .

Image of FIG. 10.
FIG. 10.

HREELS spectra of the surface at 110 K exposed to 0.5 L 3-chloropropionitrile (a) and anneal to 300 K (b). , specular geometry.

Image of FIG. 11.
FIG. 11.

C 1s XPS spectra for physisorbed and chemisorbed 3-chloropropionitrile (obtained by annealing the physisorbed multilayer-covered surface to 300 K) on .

Image of FIG. 12.
FIG. 12.

Cl 2p XPS spectra of physisorbed and chemisorbed 3-chloropropionitrile (obtained by annealing the physisorbed multilayer-covered surface to 300 K) on .

Image of FIG. 13.
FIG. 13.

N 1s XPS spectra of physisorbed and chemisorbed 3-chloropropionitrile (obtained by annealing the physisorbed multilayer-covered surface to 300 K) on .

Image of FIG. 14.
FIG. 14.

Schematic diagram for the adsorption of 3-chloropropionitrile on .

Image of FIG. 15.
FIG. 15.

HREELS spectra for low exposure (a), physisorbed multilayer (b), and annealing (b) to300 K (c) of 5-chloro-1-pentyne on the surface at 110 K. , specular geometry.

Image of FIG. 16.
FIG. 16.

Cl 2p XPS spectra for physisorbed and chemisorbed 5-chloro-1-pentyne (obtained by annealing the physisorbed multilayer-covered surface to 300 K) on the surface.

Image of FIG. 17.
FIG. 17.

C 1s XPS spectra for physisorbed and chemisorbed 5-chloro-1-pentyne (obtained by annealing the physisorbed multilayer-covered surface to 300 K) on the surface at 110 K.

Image of FIG. 18.
FIG. 18.

Schematic model of 5-chloro-1-pentyne chemisorbed on the surface.

Tables

Generic image for table
Table I.

Assignments of physisorbed and chemisorbed chloroacetonitrile (CA) on at 110 K. (All frequencies are in .)

Generic image for table
Table II.

Deconvoluted results of XPS spectra for chemisorbed and physisorbed chloroacetonitrile on the surface. (All energies are in eV.)

Generic image for table
Table III.

Assignments of physisorbed and chemisorbed propargyl chloride on . (All frequencies are in .)

Generic image for table
Table IV.

Deconvoluted results of XPS spectra for chemisorbed and physisorbed propargyl chloride on the surface. (All energies are in eV.)

Generic image for table
Table V.

Assignments of physisorbed and chemisorbed 3-chloropropionitrile (3-CP) on at 110 K. (All frequencies are in .)

Generic image for table
Table VI.

Deconvoluted results of XPS spectra for chemisorbed and physisorbed 3-chloropropionitrile on the surface. (All energies are in eV.)

Generic image for table
Table VII.

Assignments of physisorbed and chemisorbed 5-chloro-1-pentyne (5-C-1-P) on at 110 K. (All frequencies are in .)

Generic image for table
Table VIII.

Deconvoluted results of XPS spectra for chemisorbed and physisorbed 5-chloro-1-pentyne on the surface. (All energies are in eV.)

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/content/aip/journal/jcp/132/21/10.1063/1.3407442
2010-06-07
2014-04-19
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Enabling enelike reactions on Si(111)-7×7 through tuning organic molecular structures
http://aip.metastore.ingenta.com/content/aip/journal/jcp/132/21/10.1063/1.3407442
10.1063/1.3407442
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