No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Communications: Observation of two classes of isomers of hydrated electrons in sodium-water clusters
1.W. Weyl, Ann. Phys. 121, 601 (1864).
5.J. V. Coe, G. H. Lee, J. G. Eaton, S. T. Arnold, H. W. Sarkas, K. Bowen, C. Ludewigt, H. Haberland, and D. R. Worsnop, J. Chem. Phys. 92, 3980 (1990).
28.M. J. Frisch, G. W. Trucks, H. B. Schlegel et al., GAUSSIAN 03, Revision C.02, Gaussian, Incorporated, Wallingford CT, 2003.
29.R. Ahlrichs et al., TURBOMOLE V6.0 2009, a development of University of Karlsruhe and Forschungszentrum Karlsruhe, Turbomole GmbH, 2009.
Article metrics loading...
A new class of sodium-water clusters with a low lying ionization potential (IP) is characterized by their photoionizationspectra in molecular beam experiments. This implies that clusters coexist for in two forms of significant abundances being distinguished by their IPs of and . A tentative quantum chemical characterization was achieved by simulating ionizationspectra for selected cluster sizes using an ab initio molecular dynamics approach. Experiment and theory suggest that the distance is significantly larger in the clusters with the lower IP. This indicates that the solvated electron in clusters very probably forms with the counterion both a solvent separated and a contact ion pair.
Full text loading...
Most read this month