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/content/aip/journal/jcp/132/24/10.1063/1.3458912
2010-06-24
2016-09-27

Abstract

A pulsed arc discharge source was used to prepare gas-phase, aluminum hydride cluster anions, , exhibiting enhanced hydrogen content. The maximum number of hydrogen atoms in species was for , i.e., , and for , i.e., , as observed in their mass spectra. These are the most hydrogen-rich aluminum hydrides to be observed thus far, transcending the 3:1 hydrogen-to-aluminum ratio in alane. Even more striking, ion intensities for species with and hydrogen atoms were significantly higher than those of nearby mass peaks for which , i.e., the ion intensities for and for deviated from the roughly bell-shaped ion intensity patterns seen for most species, in which ranges from 1 to . Calculations based on density functional theory showed that clusters have chain and/or double-ring polymericstructures.

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