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Disparate product distributions observed in reactions with and
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10.1063/1.3313927
/content/aip/journal/jcp/132/6/10.1063/1.3313927
http://aip.metastore.ingenta.com/content/aip/journal/jcp/132/6/10.1063/1.3313927
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Mass spectra of (a) , (b) , (c) , and (d) before (black trace) and after (blue trace) exposure to . Mass scales are shifted so that peaks with the same values of are vertically aligned.

Image of FIG. 2.
FIG. 2.

Relative changes in peak intensity upon water exposure for (a) , (b) , (c) , and (d) . In the case of new product formation , the most likely cluster precursor intensity was used in the denominator.

Image of FIG. 3.
FIG. 3.

Mass spectra covering the and mass range showing (a) pre (black) and post (blue) exposure intensities, with lower initial oxide distribution, (b) pre (black) and post (blue) exposure intensities with higher initial oxide distribution, and (c) pre (black) and post (blue) exposure intensities with lower initial oxide distribution.

Image of FIG. 4.
FIG. 4.

Mass spectra of (a) , (b) , (c) , and (d) before (black trace) and after (purple trace) exposure to . Mass scales are shifted so that peaks with the same values of are vertically aligned.

Image of FIG. 5.
FIG. 5.

Relative changes in peak intensity upon exposure for (a) , (b) , (c) , and (d) . In the case of new product formation , the most likely cluster precursor intensity was used in the denominator.

Image of FIG. 6.
FIG. 6.

Mass spectra of (a) , (b) , (c) , and (d) using pure helium as carrier gas (black trace) and with seeded in the helium carrier gas (5%), so is present in the laser ablation cluster production region.

Image of FIG. 7.
FIG. 7.

Lowest energy structures and LUMOs calculated for , , , and , along with the competitive structures for and calculated in Ref. 12.

Image of FIG. 8.
FIG. 8.

Possible modes of interaction between and (a) and [(b) and (c)] , based on low-barrier interactions between and described in Ref. 11.

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/content/aip/journal/jcp/132/6/10.1063/1.3313927
2010-02-09
2014-04-20
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Disparate product distributions observed in Mo(3−x)WxOy−(x=0–3; y=3–9) reactions with D2O and CO2
http://aip.metastore.ingenta.com/content/aip/journal/jcp/132/6/10.1063/1.3313927
10.1063/1.3313927
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