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Sub-Doppler spectroscopy of mixed state levels in
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10.1063/1.3502084
/content/aip/journal/jcp/133/14/10.1063/1.3502084
http://aip.metastore.ingenta.com/content/aip/journal/jcp/133/14/10.1063/1.3502084

Figures

Image of FIG. 1.
FIG. 1.

Block diagram of sub-Doppler saturation frequency-modulation spectrometer. oscillator. -optic modulator.

Image of FIG. 2.
FIG. 2.

Section of the branch of the transition of the radical in the region of with the rotational assignments. The symbols S and T indicate the “singlet” and “triplet” components of the perturbed rotational level.

Image of FIG. 3.
FIG. 3.

(a) The absorption and (b) dispersion parts of the “singlet” component of the level, showing the 9.6 MHz hyperfine splitting associated with this level. The labeled angular momentum quantum number . The horizontal axis is in megahertz from the start of the scan.

Image of FIG. 4.
FIG. 4.

As in Fig. 3, (a) the absorption and (b) dispersion parts of the “triplet” component of the level, showing hyperfine splittings of 21.3 and 18.6 MHz.

Image of FIG. 5.
FIG. 5.

Hyperfine-resolved absorption and dispersion spectra of the (a) “singlet” and (b) “triplet” components of the perturbed rotational level. The nearly equal hyperfine splitting in the “singlet” and “triplet” components indicates almost complete mixing.

Tables

Generic image for table
Table I.

Deperturbation of levels with spin-orbit mixing.

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/content/aip/journal/jcp/133/14/10.1063/1.3502084
2010-10-12
2014-04-16
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Sub-Doppler spectroscopy of mixed state levels in CH2
http://aip.metastore.ingenta.com/content/aip/journal/jcp/133/14/10.1063/1.3502084
10.1063/1.3502084
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