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Communication: Relationships between Intermolecular potential, thermodynamics, and dynamic scaling in viscous systems
10.C. M. Roland, in Current Topics in Elastomers Research, edited by A. K. Bhowmick (CRC, Boca Raton, FL/Taylor & Francis, London, 2008), Chap. 24.
21.V. Yu. Bardik and K. S. Shakun, Ukr. J. Phys. 50, 404 (2005).
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In this communication, we provide a recipe for a consistent relation between dynamic scaling and thermodynamic properties well-grounded by the same intermolecular generalized Lennard-Jones potential, which is derived by using an essentially modified Avramov model within the framework of the “thermodynamic scaling” idea. This relation is experimentally verified very well for supercooled van der Waals liquids, and consequently, it can be a good basis for a proper universal description of molecular dynamics and thermodynamics of viscoussystems.
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