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/content/aip/journal/jcp/133/22/10.1063/1.3525644
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/content/aip/journal/jcp/133/22/10.1063/1.3525644
2010-12-14
2016-12-11

Abstract

For the first time, domains with twisted structures have been established in planar samples of achiral compounds in tilted smectic C phase. This evidences separation of molecular conformers differing in the sense of axial chirality and confirms polar symmetry of these domains. A simple model considering polar surface anchoring energy and bulk energy of the twist can account for this finding. Conditions for coexistence of twisted and homogeneous domains are discussed.

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