No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.
Communication: Photodissociation of —Frustrated NN bond breaking causes diffuse vibrational structures
1.R. P. Wayne, Chemistry of Atmospheres, 2nd ed. (Oxford University Press, Oxford, 1991).
12.MOLPRO, a package of ab initio programs designed by H. -J. Werner and P. J. Knowles, version 2006, R. Lindh, F. R. Manby, M. Schütz et al..
18.The data in Ref. 2 are, in our opinion, suspicious. First, the cross sections in Fig. 2 of Ref. 2 used for the determination of and , are slightly different from those in Fig. 3 and those measured by Yoshino et al. (Ref. 3). Second, the maximum values taken from Figs. 3 through 6 if Ref. 2 for different isotope combinations increase linearly with temperature, even for the low range. A more gradual increase would be expected from , where the contribution of can be neglected, to . Third, above 400 K or so contributions from (0,2,0) cannot be ignored.
Article metrics loading...
The photodissociation of is studied by wave packet calculations using a global three-dimensional potential energy surface for the first excited state. It is shown that the weak vibrational structures of the absorption cross section are caused by large-amplitude NN stretch motion, combined with strong excitation of the bend as well as the O–NN stretch. Weakening of the NN bond toward the channel is the necessary prerequisite.
Full text loading...
Most read this month