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Asymptotic multipolar expansion of collision-induced properties
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10.1063/1.3562210
/content/aip/journal/jcp/134/10/10.1063/1.3562210
http://aip.metastore.ingenta.com/content/aip/journal/jcp/134/10/10.1063/1.3562210

Figures

Image of FIG. 1.
FIG. 1.

The R-dependence of the symmetry-adapted components of the collision-induced dipole moment for –Ar. All SA components are indicated by their λ L indices. The long-range analytical classical multipolar components (dashed lines) are also shown. The component resulting from the quadrupole moment of is denoted by Q and the component emerging from the hexadecapole moment of by Φ. The collision diameter σ of the –Ar pair is given as well.

Image of FIG. 2.
FIG. 2.

The R-dependence of the irreducible spherical rotationally adapted components of the isotropic part the CI –He pair polarizability versus intermolecular distance R, given in atomic units. The long-range first order DID (DID) polarizability is also shown. All SA components are indicated by their λ L indices.

Image of FIG. 3.
FIG. 3.

The SA components of the anisotropic (deviator) part of the CI polarizability for –He pair. The radial behavior of the irreducible spherical symmetry adapted components is displayed. The long-range first order DID components and (DID) and (DID) are also plotted. All SA components are indicated by their λ L indices. The collision diameter σ of the -He pair is given as well.

Image of FIG. 4.
FIG. 4.

The radial dependence of the irreducible spherical symmetry adapted ab initio component of the isotropic part the CI –He pair polarizability. The long-range analytical MIM, dipole–octopole component (MIM) is also presented.

Image of FIG. 5.
FIG. 5.

The R-dependence of the irreducible spherical symmetry-adapted ab initio component of the isotropic part of the CI –Ne pair polarizability vs intermolecular distance R, given in atomic units. Long-range analytical MIM, dipole–octopole component (MIM) is also shown. The collision diameter σ for a –Ne pair varies from 5.40 to 5.66 bohr for the data taken from various sources (see Ref. 49).

Image of FIG. 6.
FIG. 6.

The radial behavior of the irreducible spherical symmetry-adapted ab initio component of the anisotropic part of the CI –He pair polarizability vs intermolecular distance R. All data are given in atomic units. Long-range analytical MIM, dipole–octopole component (MIM) is also given.

Image of FIG. 7.
FIG. 7.

The R-dependence of the irreducible spherical symmetry-adapted ab initio component of the anisotropic part of the CI –Ne pair polarizability vs intermolecular distance R, given in atomic units. Long-range analytical MIM, dipole–octopole component (MIM) is also shown.

Image of FIG. 8.
FIG. 8.

The R-dependence of the ab initio and irreducible spherical symmetry-adapted components of the anisotropic part of the –He pair polarizability vs intermolecular distance R. All data are given in atomic units. The long range analytical MIM, dipole–octopole origin components are also given.

Image of FIG. 9.
FIG. 9.

The radial behavior of the divergence between the model data [Eq. (12)] and the ab initio ones for the hyperpolarizability component of –He. All data are given in atomic units.

Tables

Generic image for table
Table I.

Values of the dipole2–quadrupole hyperpolarizability (B), dipole polarizability (α), dipole–octopole polarizability (E), and quadrupole moment (Q) used in our calculations. All values are in atomic units [a.u.].

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/content/aip/journal/jcp/134/10/10.1063/1.3562210
2011-03-14
2014-04-19
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Asymptotic multipolar expansion of collision-induced properties
http://aip.metastore.ingenta.com/content/aip/journal/jcp/134/10/10.1063/1.3562210
10.1063/1.3562210
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