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/content/aip/journal/jcp/134/3/10.1063/1.3544211
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/content/aip/journal/jcp/134/3/10.1063/1.3544211
2011-01-21
2016-12-06

Abstract

Delayed asymmetric Coulomb fission in size-selected molecular dication clusters has been recorded for the first time. Observations on (NH3) n 2+clusters show that fragmentation accompanied by charge separation can occur on a microsecond time scale, exhibits considerable asymmetry, and involves a kinetic energy release of ∼0.9 eV. The fission process has been modeled by representing the fragments as chargeddielectric spheres and the calculated maximum in the electrostatic interaction energy between the fragments gives a good account of the measured kinetic energy release. A simple kinetic model shows that instrumental factors may contribute to the observation of asymmetric fragmentation.

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