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Resonant two-photon ionization spectroscopy of jet-cooled OsN: 520–418 nm
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10.1063/1.3633694
/content/aip/journal/jcp/135/11/10.1063/1.3633694
http://aip.metastore.ingenta.com/content/aip/journal/jcp/135/11/10.1063/1.3633694

Figures

Image of FIG. 1.
FIG. 1.

Vibronic spectrum of OsN, with assigned band systems indicated.

Image of FIG. 2.
FIG. 2.

Isotope shifts and vibrational numbering of the C-X system. From this analysis, it is evident that the 19 680 cm−1 band is the 2-0 band of the system.

Image of FIG. 3.
FIG. 3.

Rotationally resolved spectrum of the 2-0 band of the C 2Φ7/2 ← X 2Δ5/2 system.

Image of FIG. 4.
FIG. 4.

Rotationally resolved spectrum of the 2-0 band of the D 2Π3/2 ← X 2Δ5/2 system.

Image of FIG. 5.
FIG. 5.

Qualitative molecular orbital diagram for OsN.

Tables

Generic image for table
Table I.

Spectroscopic constants for the C[17.8]2Φ7/2 – X 2Δ5/2 system of OsN.

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Table II.

Spectroscopic constants for the D[18.0]2Π3/2 – X 2Δ5/2 system of OsN.

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Table III.

Spectroscopic constants for the F[21.2] 2Φ7/2 – X 2Δ5/2 system of OsN.

Generic image for table
Table IV.

Spectroscopic constants for the G[22.3] 2Φ7/2 – X 2Δ5/2 system of OsN.

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Table V.

Spectroscopic constants for the E[18.1] 2Π3/2 – X 2Δ5/2 system of OsN.a

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Table VI.

Spectroscopic constants for the B[16.0] 2Π3/2 – X 2Δ5/2 system of OsN.a

Generic image for table
Table VII.

Spectroscopic constants for additional bands of OsN.

Generic image for table
Table VIII.

Summary of all experimentally known states of 192Os14N.

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/content/aip/journal/jcp/135/11/10.1063/1.3633694
2011-09-16
2014-04-19
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Resonant two-photon ionization spectroscopy of jet-cooled OsN: 520–418 nm
http://aip.metastore.ingenta.com/content/aip/journal/jcp/135/11/10.1063/1.3633694
10.1063/1.3633694
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