NOTICE: Scitation Maintenance Sunday, March 1, 2015.

Scitation users may experience brief connectivity issues on Sunday, March 1, 2015 between 12:00 AM and 7:00 AM EST due to planned network maintenance.

Thank you for your patience during this process.

1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.
f
Communication: Vacuum ultraviolet laser photodissociation studies of small molecules by the vacuum ultraviolet laser photoionization time-sliced velocity-mapped ion imaging method
Rent:
Rent this article for
Access full text Article
/content/aip/journal/jcp/135/7/10.1063/1.3626867
1.
1. X. M. Yang and K. P. Liu, Modern Trends in Chemical Reaction Dynamics: Experiment and Theory (World Scientific Publishing Co. Pte. Ltd., Singapore, 2004).
2.
2. D. W. Chandler and P. L. Houston, J. Chem. Phys. 87, 1445 (1987);
http://dx.doi.org/10.1063/1.453276
2.A. Eppink and D. H. Parker, Rev. Sci. Instrum. 68, 3477 (1997).
http://dx.doi.org/10.1063/1.1148310
3.
3. D. Townsend, M. P. Minitti, and A. G. Suits, Rev. Sci. Instrum. 74, 2530 (2003).
http://dx.doi.org/10.1063/1.1544053
4.
4. Imaging in Chemical Dynamics, edited by A. G. Suits and R. E. Continetti (American Chemical Society, Washington, DC, 2001), p. 103.
5.
5. M. L. Lipciuc, A. J. van-den-Brom, L. Dinu, and M. H. M. Janssen, Rev. Sci. Instrum. 76, 123103 (2005).
http://dx.doi.org/10.1063/1.2138691
6.
6. J. G. Zhou, K. C. Lau, E. Hassanein, H. F. Xu, S. X. Tian, B. Jones, and C. Y. Ng, J. Chem. Phys. 124, 034309 (2006).
http://dx.doi.org/10.1063/1.2158999
7.
7. W. Ubachs, L. Tashiro, and R. N. Zare, Chem. Phys. 130, 1 (1991).
http://dx.doi.org/10.1016/0301-0104(89)87031-4
8.
8. W. M. Jackson, D. D. Xu, R. J. Price, K. L. McNesby, and I. A. McLaren, ACS Symp. Ser. 770(7), 103 (2000);
http://dx.doi.org/10.1021/symposium
8.D. D. Xu, R. J. Price, J. H. Huang, and W. M. Jackson, Zeits. für Physik. Chemie 215, 253 (2001);
8.W. M. Jackson and D. D. Xu, J. Chem. Phys. 113, 3651 (2000).
http://dx.doi.org/10.1063/1.1287394
9.
9. G. Hilber, A. Lago, and R. Wallenstein, J. Opt. Soc. Am. B 4, 1753 (1987).
http://dx.doi.org/10.1364/JOSAB.4.001753
10.
10. H. Kato and M. Baba, Chem. Rev. 95, 2311 (1995).
http://dx.doi.org/10.1021/cr00039a003
11.
11. H. Helm and P. C. Cosby, J. Chem. Phys. 90(8), 4208 (1989);
http://dx.doi.org/10.1063/1.455777
11.M. O. Vieitez, T. I. Ivanov, W. Ubachs, B. R. Lewis, and C. A. de-Lange, J. Mol. Liq. 141, 110 (2008);
http://dx.doi.org/10.1016/j.molliq.2008.01.014
11.S. T. Pratt, P. M. Dehmer, and J. L. Dehmer, J. Chem. Phys. 81, 3444 (1984);
http://dx.doi.org/10.1063/1.448069
11.S. T. Pratt, E. D. Poliakoff, P. M. Dehmer, and J. L. Dehmer, J. Chem. Phys. 78, 65 (1983).
http://dx.doi.org/10.1063/1.446232
12.
12. H. Helm and P. C. Cosby, J. Chem. Phys. 90(8), 4208 (1989);
http://dx.doi.org/10.1063/1.455777
12.C. W. Walter, P. C. Cosby, and H. Helm, J. Chem. Phys. 99(5), 3553 (1993).
http://dx.doi.org/10.1063/1.466152
13.
13. J. P. Sprengers, W. Ubachs, and K. G. H. Baldwin, J. Chem. Phys. 122, 144301 (2005);
http://dx.doi.org/10.1063/1.1869985
13.M. O. Vieitez, T. I. Ivanov, W. Ubachs, B. R. Lewis, and C. A. de-Lange, J. Mol. Liq. 141, 110 (2008).
http://dx.doi.org/10.1016/j.molliq.2008.01.014
14.
14. K. Yoshino, Y. Tanaka, P. K. Carroll, and P. Mitchell, J. Mol. Spectrosc. 54, 87 (1975);
http://dx.doi.org/10.1016/0022-2852(75)90011-9
14.J. Y. Roncin, J. L. Subtil, and F. Launay, J. Mol. Spectrosc. 188, 128 (1998).
http://dx.doi.org/10.1006/jmsp.1997.7497
15.
15. B. Buijsse and W. J. van der Zande, J. Chem. Phys. 107(22), 9447 (1997).
http://dx.doi.org/10.1063/1.475241
16.
16. M. B. McElroy and D. M. Hunten, J. Geophys. Res. 75, 1188 (1970).
http://dx.doi.org/10.1029/JA075i007p01188
17.
17. G. M. Lawrence, J. Chem. Phys. 56, 3435 (1972).
http://dx.doi.org/10.1063/1.1677717
18.
18. Z. C. Chen, F. C. Liu, B. Jiang, X. M. Yang, and D. H. Parker, J. Phys. Chem. Lett. 1, 1861 (2010).
http://dx.doi.org/10.1021/jz100356f
http://aip.metastore.ingenta.com/content/aip/journal/jcp/135/7/10.1063/1.3626867
Loading
/content/aip/journal/jcp/135/7/10.1063/1.3626867
Loading

Data & Media loading...

Loading

Article metrics loading...

/content/aip/journal/jcp/135/7/10.1063/1.3626867
2011-08-15
2015-02-26

Abstract

We demonstrate that the vacuum ultraviolet (VUV)photodissociation dynamics of N2 and CO2 can be studied using VUV photoionization with time-sliced velocity-mapped ion imaging (VUV-PI-VMI) detection. The VUV laser light is produced by resonant sum frequency mixing in Kr. N2 is used to show that when the photon energy of the VUV laser is above the ionization energy of an allowed transition of one of the product atoms it can be detected and characterized as the wavelength is varied. In this case a β parameter = 0.57 for the N(2D°) was measured after exciting N2(o 1Πu, v = 2, J = 2) ← N2(X 1Σg +, v = 0, J = 1). Studies with CO2 show that when there is no allowed transition, an autoionization resonance can be used for the detection of a product atom. In this case it is shown for the first time that the O(1D) atom is produced with CO(1Σ+) at 92.21 nm. These results indicate that the VUV laser photodissociation combined with the VUV-PI-VMI detection is a viable method for studying the one-photon photodissociation from the ground state of simple molecules in the extreme ultraviolet and VUV spectral regions.

Loading

Full text loading...

/deliver/fulltext/aip/journal/jcp/135/7/1.3626867.html;jsessionid=oae62yi1wufu.x-aip-live-06?itemId=/content/aip/journal/jcp/135/7/10.1063/1.3626867&mimeType=html&fmt=ahah&containerItemId=content/aip/journal/jcp
true
true
This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Communication: Vacuum ultraviolet laser photodissociation studies of small molecules by the vacuum ultraviolet laser photoionization time-sliced velocity-mapped ion imaging method
http://aip.metastore.ingenta.com/content/aip/journal/jcp/135/7/10.1063/1.3626867
10.1063/1.3626867
SEARCH_EXPAND_ITEM