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Transition metal phthalocyanines: Insight into the electronic structure from soft x-ray spectroscopy
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10.1063/1.4738754
/content/aip/journal/jcp/137/5/10.1063/1.4738754
http://aip.metastore.ingenta.com/content/aip/journal/jcp/137/5/10.1063/1.4738754

Figures

Image of FIG. 1.
FIG. 1.

Left: Scheme of a metal phthalocyanine molecule structure. The local symmetry around the central transition metal ion is tetragonal (D 4h symmetry), the z-axis points along the normal of the molecular plane. Right: Sketch of the energy splitting as it is present for many MPc molecules, together with the corresponding orbitals. The x- and y-axis are oriented along the shortest M-N bonds.

Image of FIG. 2.
FIG. 2.

Experimental x-ray absorption L-edge spectra of ZnPc, CuPc, NiPc, CoPc, FePc, and MnPc (from top to bottom) recorded at T = 30 K. The shown energy range covers 40 eV for all curves in order to keep constant comparable energy distances.

Image of FIG. 3.
FIG. 3.

Experimental photoemission metal 2p of ZnPc, CuPc, NiPc, CoPc, FePc, and MnPc (from top to bottom) recorded at T = 300 K using a monochromatized Al K α source.

Tables

Generic image for table
Table I.

Comparison of the experimental and theoretical values for the intensity ratio I ||x, y /I ||z . See text for details.

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/content/aip/journal/jcp/137/5/10.1063/1.4738754
2012-08-02
2014-04-20
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Transition metal phthalocyanines: Insight into the electronic structure from soft x-ray spectroscopy
http://aip.metastore.ingenta.com/content/aip/journal/jcp/137/5/10.1063/1.4738754
10.1063/1.4738754
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