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Solvation structures of protons and hydroxide ions in water
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10.1063/1.4801512
/content/aip/journal/jcp/138/15/10.1063/1.4801512
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/15/10.1063/1.4801512
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

(a) O 1s XRS spectra of 0.5, 1, 2, 4, and 6 M HCl (aq). Dotted black lines indicate the spectrum of pure water for comparison, with difference spectra between water and HCl solutions enlarged and displayed in the top panel. All spectra are normalized by area from 533 to 550 eV; (b) O 1s XRS spectra of 0.5, 1, 2, 4, and 6 M NaOH (aq). Dotted black lines indicate the spectrum of pure water for comparison, with difference spectra between water and NaOH solutions enlarged and displayed in the top panel. All spectra are normalized by area from 533 to 550 eV. (c) The region of the OH absorption for 6 M NaOH (aq) is shown expanded in the inset figure.

Image of FIG. 2.
FIG. 2.

(a) SAXS scattering intensity I(Q) vs. momentum transfer Q for 0.1, 0.25, 0.5, 1 M HCl (aq); (b) SAXS scattering intensity I(Q) vs. momentum transfer Q for 0.1, 0.25, 0.5, 1 M NaOH (aq). Black dashed lines indicate the SAXS scattering curve for water.

Image of FIG. 3.
FIG. 3.

(a) Structure factor S(Q) derived from SAXS for 0.1, 0.25, 0.5, 1 M HCl (aq). Inset is an enlarged portion of Q = 0.04–0.5 Å−1; (b) structure factor S(Q) derived from SAXS for 0.1, 0.25, 0.5, 1 M NaOH (aq). Dotted black line is S(Q) for water.

Image of FIG. 4.
FIG. 4.

Structure factor S(Q) derived from SAXS for 1 m NaCl (aq) and 1 M HCl (aq).

Image of FIG. 5.
FIG. 5.

Structure factor S(Q) derived from SAXS for 1 m NaF(aq) and 1 M NaOH (aq).

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/content/aip/journal/jcp/138/15/10.1063/1.4801512
2013-04-19
2014-04-17
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Solvation structures of protons and hydroxide ions in water
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/15/10.1063/1.4801512
10.1063/1.4801512
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