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An accurate expression for the rates of diffusion-influenced bimolecular reactions with long-range reactivity
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10.1063/1.4802584
/content/aip/journal/jcp/138/16/10.1063/1.4802584
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/16/10.1063/1.4802584
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

The steady-state rate constant k s of an electron transfer reaction involving a distance-dependent sink function given by S(r) = κe −2βr ; the dimensionless reaction strength parameter λ is defined by λ = κπe −2βσ(2β2σ2 + 2βσ + 1)/(Dσβ3).

Image of FIG. 2.
FIG. 2.

The steady-state rate constant k s of the Förster energy transfer involving a distance-dependent sink function, S(r) = αr −6; the dimensionless reaction strength parameter λ is defined by λ = 4πα/(3Dσ4).

Image of FIG. 3.
FIG. 3.

The steady-state rate constant k s of the Förster energy transfer under Coulomb potential U(r) = r C /r; the sink function is given by S(r) = αr −6 and λ = 4πα/(3Dσ4).

Image of FIG. 4.
FIG. 4.

The steady-state rate constant k s of the Förster energy transfer with contact quenching; the sink function is given by S(r) = k σδ(r − σ)/(4πσ2) + αr −6 and λ = 4πα/(3Dσ4).

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/content/aip/journal/jcp/138/16/10.1063/1.4802584
2013-04-30
2014-04-18
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: An accurate expression for the rates of diffusion-influenced bimolecular reactions with long-range reactivity
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/16/10.1063/1.4802584
10.1063/1.4802584
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