1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Correlated driving and dissipation in two-dimensional spectroscopy
Rent:
Rent this article for
USD
10.1063/1.4773472
/content/aip/journal/jcp/138/2/10.1063/1.4773472
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/2/10.1063/1.4773472
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Eight Liouville-space pathways (upper) and double-sided Feynman diagrams (lower) for two-dimensional spectroscopy in the rotating-wave approximation. Each Liouville-space pathway starts from the upper-left circle, while the double-sided Feynman diagram starts from the bottom, following the convention of Ref. 12 .

Image of FIG. 2.
FIG. 2.

Linear absorption spectra of the FMO complex calculated at T = 77 K using different methods, with the molecular |e⟩-manifolds Hamiltonian of Eq. (22) . Drude dissipation parameters for each on-site excitation energy fluctuation are λ = 35 cm−1 and γ−1 = 100 fs.

Image of FIG. 3.
FIG. 3.

Absorptive 2D spectra evaluated with different methods for the same FMO model system at 77 K (a)–(d). Involved are also the 21 bi-exciton levels.

Image of FIG. 4.
FIG. 4.

Amplitude oscillations of eight cross peaks extracted from the waiting-time-resolved 2D spectra evaluated at 77 K, with “CPmn” indicating the cross peak at (ω1 = ε m , ω3 = ε n ).

Image of FIG. 5.
FIG. 5.

Linear absorption spectra for the same FMO model system calculated at T = 298 K using different methods.

Image of FIG. 6.
FIG. 6.

(a)–(d) Absorptive 2D spectra evaluated with different methods for the same FMO model system at 298 K.

Image of FIG. 7.
FIG. 7.

Amplitude oscillations of eight cross peaks extracted from the waiting-time-resolved 2D spectra evaluated at 298 K.

Loading

Article metrics loading...

/content/aip/journal/jcp/138/2/10.1063/1.4773472
2013-01-10
2014-04-24
Loading

Full text loading...

This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Correlated driving and dissipation in two-dimensional spectroscopy
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/2/10.1063/1.4773472
10.1063/1.4773472
SEARCH_EXPAND_ITEM