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Diffusion of aromatic compounds in nonaqueous solvents: A study of solute, solvent, and temperature dependences
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10.1063/1.4808216
/content/aip/journal/jcp/138/22/10.1063/1.4808216
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/22/10.1063/1.4808216

Figures

Image of FIG. 1.
FIG. 1.

Variation of 1/ with the molecular volume of solutes diffusing in cyclohexane (•) and -hexane (▲) at 298.2 K.

Image of FIG. 2.
FIG. 2.

Plot of 1/ vs at different temperatures. (a) Diffusivities from Refs. , and ; (b) -hexane data from Ref. .

Image of FIG. 3.
FIG. 3.

Solvent dependence of 1/ for each of the aromatic solutes at 298.2 K.

Tables

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Table I.

Limiting mutual diffusion coefficients ( / 10m s) in -hexane and cyclohexane at 298.15 K.

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Table II.

Parameters and statistics of linear regressions using Eq. (4) .

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Table III.

Experimental values and calculated results for nonassociated aromatic solutes in various solvents at 298.15 K.

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Table IV.

Values of , , , , , and of solvents at different temperatures.

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Table V.

Experimental and calculated tracer diffusivities at different temperatures.

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/content/aip/journal/jcp/138/22/10.1063/1.4808216
2013-06-10
2014-04-19
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Diffusion of aromatic compounds in nonaqueous solvents: A study of solute, solvent, and temperature dependences
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/22/10.1063/1.4808216
10.1063/1.4808216
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