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Quantum defects at the critical charge
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10.1063/1.4808357
/content/aip/journal/jcp/138/22/10.1063/1.4808357
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/22/10.1063/1.4808357

Figures

Image of FIG. 1.
FIG. 1.

The 2 quantum defect in the Li (1 2)  isoelectronic sequence. The integer values, obtained from the NIST ionization energies, are denoted by asterisks. The fractional values, obtained from Hartree-Fock ionization energies, are denoted by circles.

Image of FIG. 2.
FIG. 2.

The overlap integral between the Hartree-Fock 2 orbital in the Li (1 2)  isoelectronic sequence and a hydrogen-like 1 orbital.

Image of FIG. 3.
FIG. 3.

The 2 quantum defect in the B (1 2 2)  isoelectronic sequence. The integer values, obtained from the NIST ionization energies, are denoted by asterisks. For fractional values, the quantum defects obtained from Hartree-Fock ionization energies are denoted by circles, and those obtained from the correlated wavefunction are denoted by boxes.

Image of FIG. 4.
FIG. 4.

(a) The overlap integral between the Hartree-Fock 2 orbital in the B (1 2 2)  isoelectronic sequence and a hydrogen-like 2 orbital. (b) Same as (a), zooming in on the minimum of the curve.

Tables

Generic image for table
Table I.

Quantum defects of the outermost electron in ground- and singly excited states of the alkali atoms, near the critical charge.

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/content/aip/journal/jcp/138/22/10.1063/1.4808357
2013-06-11
2014-04-17
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Quantum defects at the critical charge
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/22/10.1063/1.4808357
10.1063/1.4808357
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