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Rate equation approach to understanding the ion-catalyzed formation of peptides
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10.1063/1.4811280
/content/aip/journal/jcp/138/24/10.1063/1.4811280
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/24/10.1063/1.4811280

Figures

Image of FIG. 1.
FIG. 1.

Normalized concentrations of peptides containing amino acid monomers in the reaction mixtures with different concentrations of NaCl: experimental data (symbols) and theoretical fits (lines + symbols). The fit at = 1.01 is the same for the CDI only and the CDI + 1.0M NaCl data.

Image of FIG. 2.
FIG. 2.

Same as Fig. 1 but with KCl.

Image of FIG. 3.
FIG. 3.

Ratios versus at different concentrations of KCl and NaCl: experiment (symbols) and theory (lines + symbols).

Image of FIG. 4.
FIG. 4.

Reaction scheme: (a) reversible activation of a peptide monomer with CDI; (b) irreversible reaction chain producing peptides ( = 1,2,3…).

Image of FIG. 5.
FIG. 5.

Evolution of () at = 1/2.

Tables

Generic image for table
Table I.

Fitting values of , the estimated values, and the ratios of KCl to NaCl-catalyzed rate constants at different salt concentrations.

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/content/aip/journal/jcp/138/24/10.1063/1.4811280
2013-06-26
2014-04-16
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Rate equation approach to understanding the ion-catalyzed formation of peptides
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/24/10.1063/1.4811280
10.1063/1.4811280
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