1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Solvation at nanoscale: Alkali-halides in water clusters
Rent:
Rent this article for
USD
10.1063/1.4775586
/content/aip/journal/jcp/138/4/10.1063/1.4775586
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/4/10.1063/1.4775586

Figures

Image of FIG. 1.
FIG. 1.

Schematic view of experiment: (1) water storage, (2) water oven, (3) nozzle, (4) skimmer, (5) oven and interaction region, (6) Scienta R4000 hemispherical electron analyzer, and (7) liquid nitrogen cooled cold trap.

Image of FIG. 2.
FIG. 2.

(a) A typical photoelectron spectrum containing both molecular and cluster features measured using photon energy of 79.6 eV. (b) Measured H2O molecular outer-valence (labels 1–3) and inner-valence (label 4) features, valence and K 3p features of KI molecule (labels 5 and 6, respectively), and He 1s line (label 7). (c) Water cluster photoelectron spectrum (labels 1–4), valence and K 3p features of KI wet clusters (labels 5 and 6, respectively).

Image of FIG. 3.
FIG. 3.

Sodium 2p photoelectron spectrum of (a) NaF, (b) NaCl, and (c) NaBr vapor and wet-salt clusters.

Image of FIG. 4.
FIG. 4.

Potassium 3p photoelectron spectrum of (a) KCl, (b) KBr, and (c) KI vapor and wet-salt clusters.

Image of FIG. 5.
FIG. 5.

Chloride 2p photoelectron spectrum of (a) NaCl and (b) KCl vapor and wet-salt clusters.

Image of FIG. 6.
FIG. 6.

Bromide 3d photoelectron spectrum of (a) NaBr and (b) KBr vapor and wet-salt clusters.

Image of FIG. 7.
FIG. 7.

Iodide 4d photoelectron spectrum of KI vapor (dotted line) and vapor and wet-salt clusters (solid line).

Tables

Generic image for table
Table I.

The binding energies of the valence spectrum of H2O molecule, (H2O) n clusters and liquid water. All values are in electron volts.

Generic image for table
Table II.

Experimental binding energies of alkali cations and halide anions in wet-salt clusters E(wetcl.), aqueous solutions E(aq.), dry alkali–halide clusters E(drycl.), and monomers E(mon.). Two values refer to the different spin-orbit states.

Loading

Article metrics loading...

/content/aip/journal/jcp/138/4/10.1063/1.4775586
2013-01-22
2014-04-25
Loading

Full text loading...

This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Solvation at nanoscale: Alkali-halides in water clusters
http://aip.metastore.ingenta.com/content/aip/journal/jcp/138/4/10.1063/1.4775586
10.1063/1.4775586
SEARCH_EXPAND_ITEM