No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Comment on “On the theoretical determination of the Prigogine-Defay ratio in glass transition” [J. Chem. Phys.136, 124502 (2012)]
7. J.-L. Garden
, H. Guillou
, J. Richard
, and L. Wondraczek
, e-print arXiv:1004.1272v1
9. I. Gutzow and J. Schmelzer, The Vitreous State (Springer, 1995).
11. I. Prigogine and R. Defay, Chemical Thermodynamics (Longmans, 1954).
Article metrics loading...
Generally, experimentally determined values of the Prigogine-Defay (PD) ratio are different from unity. This can be explained if one considers that more than one single order parameter are involved in the thermodynamics of the glass transition process. Against the consensual view, Tropin et al. demonstrated that PD ratios can be different from unity even if one single order parameter is involved. This “Comment” aims to discuss fundamental mistakes leading to this conclusion in the recent article “On the theoretical determination of the Prigogine-Defay ratio in glass transition” [J. Chem. Phys.136, 124502 (Year: 2012)] by Tropin et al. 10.1063/1.3694531
Full text loading...
Most read this month