1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
f
Communication: IR spectroscopy of neutral transition metal clusters through thermionic emission
Rent:
Rent this article for
Access full text Article
/content/aip/journal/jcp/139/12/10.1063/1.4822324
1.
1. I. M. L. Billas, A. Chatelain, and W. A. de Heer, Science 265, 1682 (1994).
http://dx.doi.org/10.1126/science.265.5179.1682
2.
2. D. K. Böhme and H. Schwarz, Angew. Chem., Int. Ed. 44, 2336 (2005).
http://dx.doi.org/10.1002/anie.200461698
3.
3. G. von Helden, M. T. Hsu, P. R. Kemper, and M. T. Bowers, J. Chem. Phys. 95, 3835 (1991).
http://dx.doi.org/10.1063/1.460783
4.
4. F. Furche, R. Ahlrichs, P. Weis, C. Jacob, S. Gilb, T. Bierweiler, and M. M. Kappes, J. Chem. Phys. 117, 6982 (2002).
http://dx.doi.org/10.1063/1.1507582
5.
5. D. Schooss, M. N. Blom, J. H. Parks, B. von Issendorff, H. Haberland, and M. M. Kappes, Nano Lett. 5, 1972 (2005).
http://dx.doi.org/10.1021/nl0513434
6.
6. K. J. Taylor, C. L. Pettiettehall, O. Cheshnovsky, and R. E. Smalley, J. Chem. Phys. 96, 3319 (1992).
http://dx.doi.org/10.1063/1.461927
7.
7. H. Häkkinen, B. Yoon, U. Landman, X. Li, H. J. Zhai, and L. S. Wang, J. Phys. Chem. A 107, 6168 (2003).
http://dx.doi.org/10.1021/jp035437i
8.
8. M. B. Knickelbein and S. Yang, J. Chem. Phys. 93, 5760 (1990).
http://dx.doi.org/10.1063/1.459570
9.
9. M. B. Knickelbein and W. J. C. Menezes, Phys. Rev. Lett. 69, 1046 (1992).
http://dx.doi.org/10.1103/PhysRevLett.69.1046
10.
10. A. Fielicke, A. Kirilyuk, C. Ratsch, J. Behler, M. Scheffler, G. von Helden, and G. Meijer, Phys. Rev. Lett. 93, 023401 (2004).
http://dx.doi.org/10.1103/PhysRevLett.93.023401
11.
11. A. Fielicke, C. Ratsch, G. von Helden, and G. Meijer, J. Chem. Phys. 122, 091105 (2005).
http://dx.doi.org/10.1063/1.1872834
12.
12. G. von Helden, I. Holleman, G. M. H. Knippels, A. F. G. van der Meer, and G. Meijer, Phys. Rev. Lett. 79, 5234 (1997).
http://dx.doi.org/10.1103/PhysRevLett.79.5234
13.
13. G. von Helden, I. Holleman, M. Putter, A. J. A. van Roij, and G. Meijer, Chem. Phys. Lett. 299, 171 (1999).
http://dx.doi.org/10.1016/S0009-2614(98)01259-7
14.
14. D. van Heijnsbergen, G. von Helden, M. A. Duncan, A. van Roij, and G. Meijer, Phys. Rev. Lett. 83, 4983 (1999).
http://dx.doi.org/10.1103/PhysRevLett.83.4983
15.
15. D. van Heijnsbergen, A. Fielicke, G. Meijer, and G. von Helden, Phys. Rev. Lett. 89, 013401 (2002).
http://dx.doi.org/10.1103/PhysRevLett.89.013401
16.
16. G. von Helden, D. van Heijnsbergen, and G. Meijer, J. Phys. Chem. A 107, 1671 (2003).
http://dx.doi.org/10.1021/jp021982s
17.
17. J. M. Bakker, V. J. F. Lapoutre, B. Redlich, J. Oomens, B. G. Sartakov, A. Fielicke, G. von Helden, G. Meijer, and A. F. G. van der Meer, J. Chem. Phys. 132, 074305 (2010).
http://dx.doi.org/10.1063/1.3313926
18.
18. M. Haertelt, V. J. F. Lapoutre, J. M. Bakker, B. Redlich, A. Fielicke, and G. Meijer, J. Phys. Chem. Lett. 2, 1720 (2011).
http://dx.doi.org/10.1021/jz200771w
19.
19. H. Kietzmann, J. Morenzin, P. S. Bechthold, G. Ganteför, and W. Eberhardt, J. Chem. Phys. 109, 2275 (1998).
http://dx.doi.org/10.1063/1.476853
20.
20. T. Leisner, K. Athanassenas, O. Echt, O. Kandler, D. Kreisle, and E. Recknagel, Z. Phys. D: At., Mol. Clusters 20, 127 (1991).
http://dx.doi.org/10.1007/BF01543954
21.
21. A. Amrein, R. Simpson, and P. Hackett, J. Chem. Phys. 95, 1781 (1991).
http://dx.doi.org/10.1063/1.461026
22.
22. K. Athanassenas, T. Leisner, U. Frenzel, and D. Kreisle, Ber. Bunsenges. Phys. Chem. 96, 1192 (1992).
http://dx.doi.org/10.1002/bbpc.19920960921
23.
23. T. G. Dietz, M. A. Duncan, D. E. Powers, and R. E. Smalley, J. Chem. Phys. 74, 6511 (1981).
http://dx.doi.org/10.1063/1.440991
24.
24. V. E. Bondybey and J. H. English, J. Chem. Phys. 74, 6978 (1981).
http://dx.doi.org/10.1063/1.441064
25.
25. M. A. Duncan, Rev. Sci. Instrum. 83, 041101 (2012).
http://dx.doi.org/10.1063/1.3697599
26.
26. A. Fielicke, C. Ratsch, G. von Helden, and G. Meijer, J. Chem. Phys. 127, 234306 (2007).
http://dx.doi.org/10.1063/1.2806176
27.
27. J. Oomens, B. G. Sartakov, G. Meijer, and G. von Helden, Int. J. Mass Spectrom. 254, 1 (2006).
http://dx.doi.org/10.1016/j.ijms.2006.05.009
28.
28. J. M. Bakker, T. Besson, J. Lemaire, D. Scuderi, and P. Maitre, J. Phys. Chem. A 111, 13415 (2007).
http://dx.doi.org/10.1021/jp074935e
29.
29. P. V. Nhat and M. T. Nguyen, J. Phys. Chem. A 116, 7405 (2012).
http://dx.doi.org/10.1021/jp302279j
30.
30. J. G. Black, E. Yablonovitch, N. Bloembergen, and S. Mukamel, Phys. Rev. Lett. 38, 1131 (1977).
http://dx.doi.org/10.1103/PhysRevLett.38.1131
31.
31. S. S. Alimpiev, B. O. Zikrin, B. G. Sartakov, and E. M. Khokhlov, Sov. Phys. JETP 56, 943 (1982).
32.
32. V. Bagratashvili, V. S. Letokhov, A. Makarov, and E. A. Ryabov, Multiple Photon Infrared Laser Photophysics and Photochemistry (Academic Publishers, Harwood, 1985).
http://aip.metastore.ingenta.com/content/aip/journal/jcp/139/12/10.1063/1.4822324
Loading
/content/aip/journal/jcp/139/12/10.1063/1.4822324
Loading

Data & Media loading...

Loading

Article metrics loading...

/content/aip/journal/jcp/139/12/10.1063/1.4822324
2013-09-25
2014-09-20

Abstract

The resonant multiple photon excitation of neutral niobium clusters using tunable infrared (IR) radiation leads to thermionic emission. By measuring the mass-resolved ionization yield as a function of IR wavenumber species selective IR spectra are obtained for Nb ( = 5–20) over the 200–350 cm−1 spectral range. The IR resonance-enhanced multiple photon ionization spectra obtained this way are in good agreement with those measured using IR photodissociation of neutral Nb -Ar clusters. An investigation of the factors determining the applicability of this technique identifies the internal energy threshold towards thermionic emission in combination with a minimum required photon flux that rapidly grows as a function of excitation wavelength.

Loading

Full text loading...

/deliver/fulltext/aip/journal/jcp/139/12/1.4822324.html;jsessionid=51choprm8j22n.x-aip-live-03?itemId=/content/aip/journal/jcp/139/12/10.1063/1.4822324&mimeType=html&fmt=ahah&containerItemId=content/aip/journal/jcp
true
true
This is a required field
Please enter a valid email address
This feature is disabled while Scitation upgrades its access control system.
This feature is disabled while Scitation upgrades its access control system.
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Communication: IR spectroscopy of neutral transition metal clusters through thermionic emission
http://aip.metastore.ingenta.com/content/aip/journal/jcp/139/12/10.1063/1.4822324
10.1063/1.4822324
SEARCH_EXPAND_ITEM