Skip to main content
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
The full text of this article is not currently available.
1. W. Schön, S. Krüdener, F. Melchert, K. Rinn, M. Wagner, E. Salzborn, M. Karemera, S. Szücs, M. Terao, D. Fussen, R. Janev, X. Urbain, and F. Brouillard, Phys. Rev. Lett. 59, 15651568 (1987).
2. M. I. Chibisov, R. K. Janev, F. Brouillard, D. Fussen, S. Szücs, and X. Urbain, J. Phys. B 31, 2795 (1998).
3. A. B. Voitkiv, Phys. Rev. Lett. 111, 043201 (2013).
4. R. Johnsen and M. A. Biondi, Phys. Rev. A 20, 87 (1979).
5. C. H. Cherkani, S. Szucs, S. Hus, and F. Brouillard, J. Phys. B 24, 2367 (1991).
6. T. M. Miller, N. S. Shuman, and A. A. Viggiano, J. Chem. Phys. 136, 204306 (2012).
7. A. Naji, K. Olamba, J. P. Chenu, S. Szücs, M. Chibisov, and X. Urbain, J. Phys. B 31, 2961 (1998).
8. A. A. Buchachenko, T. G. Wright, E. P. F. Lee, and L. A. Viehland, J. Phys. Chem. A 113, 14431 (2009).
9. N. S. Shuman, T. M. Miller, A. A. Viggiano, and J. Troe, Adv. At., Mol., Opt. Phys. 61, 209294 (2012).
10. D. Smith and P. Spanel, Adv. At., Mol., Opt. Phys. 32, 307343 (1994).
11. N. S. Shuman, T. M. Miller, C. M. Caples, and A. A. Viggiano, J. Phys. Chem. A 114, 11100 (2010).
12. N. S. Shuman, T. M. Miller, R. Johnsen, and A. A. Viggiano, “Mutual neutralization of atomic rare-gas cations (Ne+, Ar+, Kr+, Xe+) with atomic halide anions (Cl, Br, I),” J. Chem. Phys. (unpublished).
13. R. D. Thomas, H. T. Schmidt, G. Andler, M. Bjorkhage, M. Blom, L. Brannholm, E. Backstrom, H. Danared, S. Das, N. Haag, P. Hallden, F. Hellberg, A. I. S. Holm, H. A. B. Johansson, A. Kallberg, G. Kallersjo, M. Larsson, S. Leontein, L. Liljeby, P. Lofgren, B. Malm, S. Mannervik, M. Masuda, D. Misra, A. Orban, A. Paal, P. Reinhed, K. G. Rensfelt, S. Rosen, K. Schmidt, F. Seitz, A. Simonsson, J. Weimer, H. Zettergren, and H. Cederquist, Rev. Sci. Instrum. 82, 065112 (2011).

Data & Media loading...


Article metrics loading...



We present experimental evidence that reactions of argon cations Ar+ with the halogen anions Br and I do not occur exclusively by mutual neutralization, but also produce the cations Br+ or I+ ions by transfer ionization (TI). The experiments were carried out in flowing-afterglow plasmas at gas temperatures between and 300 and 500 K, and employed a variant of the Variable Electron and Neutral Density Attachment Mass Spectrometry method. The measured TI rate coefficients are 1.9 ± 0.6 × 10−9 cm3 s−1 and × 10−9 cm3 s−1 for the Br and I reactions, respectively. We find that the TI rate coefficients decline with temperature as T−0.5 to T−1. No indication of TI was found in the reaction with Cl, where it is endoergic.


Full text loading...


Access Key

  • FFree Content
  • OAOpen Access Content
  • SSubscribed Content
  • TFree Trial Content
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd