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1. A. G. Volkov, Liquid Interfaces in Chemical, Biological, and Pharmaceutical Application (Marcel Dekker, New York, 2001).
2. H. H. Girault, Electroanal. Chem. 23, 1 (2010).
3. H. Watarai, N. Teramae, and T. Sawada, Interfacial Nanochemistry (Kluwer Academic/Plenum Publishers, New York, 2005).
4. H. Tanida, Spectrochim. Acta B 59, 1071 (2004).
5. I. Watanabe, H. Tanida, S. Kawauchi, M. Harada, and M. Nomura, Rev. Sci. Instrum. 68, 3307 (1997).
6. H. Tanida and M. Ishii, Nucl. Instrum. Methods Phys. Res. A 467-468, 1564 (2001).
7. H. Tanida, H. Nagatani, and I. Watanabe, J. Chem. Phys. 118, 10369 (2003).
8. H. Nagatani, H. Tanida, T. Ozeki, and I. Watanabe, Langmuir 22, 209 (2006).
9. H. Nagatani, H. Tanida, I. Watanabe, and T. Sagara, Anal. Sci. 25, 475 (2009).
10. H. Nagatani, H. Tanida, M. Harada, M. Asada, and T. Sagara, J. Phys. Chem. C 114, 18583 (2010).
11. H. Tanida, H. Nagatani, and M. Harada, J. Phys.: Conf. Ser. 83, 012019 (2007).
12. H. Tanida, H. Nagatani, and M. Harada, J. Phys.: Conf. Ser. 190, 012061 (2009).
13. B. Hou, N. Laanait, H. Yu, W. Bu, J. Yoon, B. Lin, M. Meron, G. Luo, P. Vanysek, and M. L. Schlossman, J. Phys. Chem. B 117, 5365 (2013).
14. N. Laanait, M. Mihaylov, B. Hou, H. Yu, P. Vanýsek, M. Meron, B. Lin, I. Benjamin, and M. L. Schlossman, Porc. Natl. Acad. Sci. U.S.A. 109, 20326 (2012).
15. N. Laanait, J. Yoon, B. Hou, P. Vanysek, M. Meron, B. Lin, G. Luo, I. Benjamin, and M. L. Schlossman, J. Chem. Phys. 132, 171101 (2010).
16. B. L. Henke, E. M. Gullikson, and J. C. Davis, At. Data Nucl. Data Tables 54, 181 (1993).
17. Y. Cheng and D. J. Schiffrin, J. Electroanal. Chem. 409, 9 (1996).
18. Y. Cheng and D. J. Schiffrin, J. Electroanal. Chem. 429, 37 (1997).
19.See supplementary material at for the electrochemical data and the EXAFS analysis based on the single-shell model. [Supplementary Material]
20. V. Mosquera, J. M. Del Río, D. Attwood, M. García, M. N. Jones, G. Prieto, M. J. Suarez, and F. Sarmiento, J. Colloid Interface Sci. 206, 66 (1998).
21. M. Harada, H. Satou, and T. Okada, J. Phys. Chem. B 111, 12136 (2007).
22. M. Harada and T. Okada, J. Chromatogr A 1085, 3 (2005).
23. T. Okada and M. Harada, Anal. Chem. 76, 4564 (2004).
24. A. R. Campanelli and L. Scaramuzza, Acta Cryst. C42, 1380 (1986).
25. S. Kamitori, Y. Sumimoto, K. Vongbupnimit, K. Noguchi, and K. Okuyama, Mol. Cryst. Liq. Cryst. 300, 31 (1997).
26. H. Nagatani, D. J. Fermín, and H. H. Girault, J. Phys. Chem. B 105, 9463 (2001).
27. T. Kakiuchi, J. Electroanal. Chem. 496, 137 (2001).

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Total-reflection X-ray absorption fine structure (TR-XAFS) technique was applied for the first time to an interface between two immiscible electrolyte solutions under potentiostatic control. The hydration structure of bromide ions was investigated at polarized 2-octanone/water interfaces. TR-XAFS spectra at Br K-edge measured in the presence of hexyltrimethylammonium bromide (CTAB) were slightly modified depending on the Galvani potential difference ( ). The extended X-ray absorption fine structure analysis exposed hydration structure changes of bromide ions at the polarized interface. The coordination structure of bromide ions at the interface could be analyzed as compared with bromide ions dissolved in aqueous solution and Br-exchanged resin having quaternary ammonium groups. The results indicated that bromide ions were associated with CTA+ at the polarized interface. The relative contribution of ion association form of bromide ions with quaternary ammonium groups was enhanced at a potential close to the ion transfer of CTA+, where the interfacial concentration of CTA+ is increased as a function of .


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