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Communication: State mixing by spin-orbit coupling in the anionic chloroiodine dissociations
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/content/aip/journal/jcp/140/4/10.1063/1.4862684
2014-01-27
2014-09-17

Abstract

Three spin-orbit states, 12Π, 22Π, and 22Π, of chloroiodine anion (ICl) formed by low-energy electron attachment in the Franck-Condon region are associated with the dissociative limits of I (1S) and Cl (2P) or Cl* (2P) fragments. Within the adiabatic scheme, the presumptive Π-symmetry of the fragment angular distributions is dramatically changed to be the Π-Σ mixing symmetry, due to the significant spin-orbit interaction effect on the electronic state couplings of ICl. The present experimental approach also enables us to separate the contributions of different electronic states from the mixed states, providing a crucial method for quantitatively evaluating the configuration-interaction wavefunctions.

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Scitation: Communication: State mixing by spin-orbit coupling in the anionic chloroiodine dissociations
http://aip.metastore.ingenta.com/content/aip/journal/jcp/140/4/10.1063/1.4862684
10.1063/1.4862684
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