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/content/aip/journal/jcp/141/24/10.1063/1.4904440
2014-12-22
2016-12-03

Abstract

The visible spectrum of is studied using high-sensitivity action spectroscopy in a cryogenic radiofrequency multipole trap. Advances are made to measure the weak ro-vibrational transitions from the lowest rotational states of up to high excitation energies providing visible line intensities and, after normalisation to an infrared calibration line, the corresponding Einstein coefficients. predictions for the Einstein coefficients are obtained from a highly precise dipole moment surface of and found to be in excellent agreement, even in the region where states have been classified as chaotic.

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