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Communication: Visible line intensities of the triatomic hydrogen ion from experiment and theory
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The visible spectrum of
is studied using high-sensitivity action spectroscopy in a cryogenic radiofrequency multipole trap. Advances are made to measure the weak ro-vibrational transitions from the lowest rotational states of
up to high excitation energies providing visible line intensities and, after normalisation to an infrared calibration line, the corresponding Einstein B coefficients.
predictions for the Einstein B coefficients are obtained from a highly precise dipole moment surface of
and found to be in excellent agreement, even in the region where states have been classified as chaotic.
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