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/content/aip/journal/jcp/142/5/10.1063/1.4906874
1.
1.R. E. Miller, Science 240, 447 (1988).
http://dx.doi.org/10.1126/science.240.4851.447
2.
2.N. Moazzen-Ahmadi and A. R. W. McKellar, Int. Rev. Phys. Chem. 32, 611 (2013).
http://dx.doi.org/10.1080/0144235X.2013.813799
3.
3.J. D. McMahon and J. R. Lane, J. Chem. Phys. 135, 154309 (2011).
http://dx.doi.org/10.1063/1.3653230
4.
4.R. Bukowski et al., J. Chem. Phys. 110, 3785 (1999).
http://dx.doi.org/10.1063/1.479108
5.
5.L. Frommhold, Collision Induced Absorption in Gases (Cambridge University Press, Cambridge, 1993).
6.
6.Y. I. Baranov, W. J. Lafferty, and G. T. Fraser, J. Mol. Spectrosc. 228, 432 (2004).
http://dx.doi.org/10.1016/j.jms.2004.04.010
7.
7.Y. I. Baranov, W. J. Lafferty, G. T. Fraser, and A. A. Vigasin, J. Mol. Spectrosc. 218, 260 (2003).
http://dx.doi.org/10.1016/S0022-2852(02)00093-0
8.
8.B. Bezard, C. D. Bergh, D. Crisp, and J.-P. Maillard, Nature 345, 508 (1990).
http://dx.doi.org/10.1038/345508a0
9.
9.M. O. Bulanin, A. B. Dokuchaev, M. V. Tonkov, and N. N. Filippov, J. Quant. Spectrosc. Radiat. Transfer 31, 521 (1984).
http://dx.doi.org/10.1016/0022-4073(84)90059-1
10.
10.L. Ozanne, J.-M. Hartmann, J.-P. Bouanich, and C. Boulet, Chem. Phys. Lett. 261, 353 (1996).
http://dx.doi.org/10.1016/0009-2614(96)00966-9
11.
11.See supplementary material at http://dx.doi.org/10.1063/1.4906874 for experimental details, binary absorption coefficients, symmetric-top modeling, and pressure dependence of dimer band shape.[Supplementary Material]
12.
12.S. Stefani et al., J. Quant. Spectrosc. Radiat. Transfer 117, 21 (2013).
http://dx.doi.org/10.1016/j.jqsrt.2012.11.019
13.
13.A. A. Vigasin, J. Mol. Spectrosc. 200, 89 (2000).
http://dx.doi.org/10.1006/jmsp.1999.8022
14.
14.G. Herzberg, Molecular Spectra and Molecular Structure. Vol. II. Infrared and Raman Spectra of Polyatomic Molecules (Krieger, Malabar, 1991).
15.
15.M. V. Tonkov, N. N. Filippov, Y. M. Timofeev, and A. V. Polyakov, J. Quant. Spectrosc. Radiat. Transfer 56, 783 (1996).
http://dx.doi.org/10.1016/S0022-4073(96)00113-6
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/content/aip/journal/jcp/142/5/10.1063/1.4906874
2015-02-02
2016-12-06

Abstract

Non-intrusive spectroscopic probing of weakly bound van der Waals complexes forming in gaseous carbon dioxide is generally performed at low pressures, for instance in supersonic jets, where the low temperature favors dimers, or in few-atmosphere samples, where the signature of dimers varying as the squared gas density is entangled with the dominating collision-induced absorption. We report experimental and theoretical results on CO dimers at very high pressures approaching the liquid phase. We observe that the shape of the CO-dimer bands undergoes a distinctive line-mixing transformation, which reveals an unexpected stability of the dimers despite the collisions with the surrounding particles and negates the common belief that CO dimers are short-lived complexes. Our results furnish a deeper insight allowing a better modeling of CO-rich atmospheres and provide also a new spectroscopic tool for studying the robustness of molecular clusters.

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