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/content/aip/journal/jcp/143/8/10.1063/1.4929568
2015-08-25
2016-12-04

Abstract

Precision measurements are performed on highly excited vibrational quantum states of molecular hydrogen. The = 12, = 0 − 3 rovibrational levels of H ( ), lying only 2000 cm−1 below the first dissociation limit, were populated by photodissociation of HS and their level energies were accurately determined by two-photon Doppler-free spectroscopy. A comparison between the experimental results on = 12 level energies with the best calculations shows a good agreement, where the present experimental accuracy of 3.5 × 10−3 cm−1 is more precise than theory, hence providing a gateway to further test theoretical advances in this benchmark quantum system.

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