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Isotope Fractionation Studies of Reactions with Cleavage of a Carbon‐14 to Hydrogen Bond in the Rate‐Determining Step
1.J. Bigeleisen, J. Chem. Phys. 17, 675 (1949).
2.Halloway, Cohen, and Westheimer, J. Am. Chem. Soc. 73, 65 (1951);
2.F. H. Westheimer and N. Nicolaides, J. Am. Chem. Soc. 71, 25 (1949)., J. Am. Chem. Soc.
3.E. M. Hodnett and L. Kaplan, Abstracts of the 125th Meeting of the American Chemical Society, Kansas City, Missouri, Spring, 1954.
4.L. P. Hammett, Physical Organic Chemistry (McGraw‐Hill Book Company, Inc., New York, 1940), Chapter VIII.
5.Ropp, Bonner, Clark, and Raaen, J. Am. Chem. Soc. 76, 1710 (1954).
6.Some cases to which such reasoning has been previously applied are mentioned by Yankwich: P. E. Yankwich and R. L. Belford, J. Am. Chem. Soc. 76, 3067 (1954).
7.L. Kaplan, J. Am. Chem. Soc. 77, 5469 (1955). The authors wish to thank Dr. Kaplan for a prepublication copy of his manuscript and for very helpful discussions of the mechanism of this reaction.
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