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Irreversible Electrochemical Processes of Membranes
1.Zwolinski, Eyring, and Reese, J. Phys. & Colloid Chem. 53, 1426 (1949);
1.R. B. Parlin and H. Eyring, Ion Transport Across Membrane (Academic Press, Inc., New York, 1954), p. 103.
2.K. H. Meyer and J. F. Sievers, Helv. Chim. Acta 19, 649, 665 (1936).
3.T. Teorell, Proc. Soc. Exptl. Biol. Med. 33, 282 (1935);
3.T. Teorell, Trans. Faraday Soc. 33, 1053 (1937);
3.T. Teorell, Z. Elektrochem. 55, 460 (1949).
4.M. Nagasawa and Y. Kobatake, J. Phys. Chem. 56, 1017 (1952).
5.Glasstone, Laidler, and Eyring, The Theory of Rate Process (McGraw‐Hill Book Company, Inc., New York, 1940).
6.S. R. De Groot, Thermodynamics of Irreversible Processes (North‐Holland Publishing Company, Amsterdam, 1952), Chaps. VII, X.
7.I. Prigogine, Introduction to Thermodynamics of Irreversible Processes (Springfield, Illinois, 1955), Chaps. III, IV, V.
8.The total ionic concentration in the membrane is given by . Inserting Eq. (14) for and intergrating we obtain . Of course we may use these expressions in Eq. (17), but they consist of as many as four constants such as . While, it will be easily shown from the condition of electrical neutrality that . Therefore, and may be expressed as These expressions have only three constants. For the sake of smplification we used these expressions.
9.M. Smoluchowski, Physik Z. 9, 529 (1905).
10.Y. Kobatake, J. Chem. Soc. Japan 77, 878 (1956).
11.Strictly speaking, cannot be regarded as a constant in the integration of as it changes slightly with ionic concentration ( contains ). However, as is easily shown from the expansion of its dependence on concentration is very small.
12.K. Sollner and H. P. Gregor, J. Phys. Chem. 54, 330 (1950).
12.Sollner, Dray, Grim, and Neihof, Ion Transport Across Membrane (Academic Press, Inc., New York, 1954), p. 144.
13.E. Manegold and K. Viets, Kolloid‐Z. 56, 7 (1931).
14.E. Bethe and Y. Terada, Z. Physik. Chem. 109, 199 (1924).
15.J. S. Mackie and P. Meares, Proc. Roy. Soc. (London) A232, 498, 510 (1955).
16.M. R. J. Wyllie, J. Phys. Chem. 58, 67 (1954).
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