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Strength of the N–N Bond in Tetrafluorohydrazine
1.E. D. Loughran and C. Mader, J. Chem. Phys. 32, 1578 (1960).
2.C. B. Colburn and A. Kennedy, J. Am. Chem. Soc. 80, 5004 (1958).
3.After consideration of our N‐N bond energy, Loughran and Mader agree that the value of 11.8 ev is probably the ionization potential of They suggest the following set of mechanisms: . There was also a break in their appearance potential curve for at 12.5 ev and they suggest the process which gives an N‐N bond strength of 16–25 kcal/mole in excellent agreement with that reported herein; however, another possibility is an excited state of the (Private communication to the authors from C. L. Mader and E. D. Loughran.)
4.R. M. Reese and V. H. Dibeler, J. Chem. Phys. 24, 1175 (1956).
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