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Isenthalpic Solidification and the Specific Heat of Supercooled Liquid Phosphorus
1.S. E. Rodriguez and C. J. Pings, J. Chem. Phys. 42, 2435–2437 (1965).
2.H. S. Chen and D. Turnbull, Bull. Am. Phys. Soc. 11, 329–330 (1966).
3.S. Y. Shiraishi and R. G. Ward, Can. Met. Quart. 3, 117–122 (1964).
4.G. A. Colligan and J. M. Lo, Tech. Rept. SCP‐4, ONR, Thayer School of Engineering, Dartmouth College, Hanover, N.H., October 1965.
5.A. G. Turnbull, Z. Physik. Chem. (Frankfurt) 42, 243–246 (1964).
6.D. Ofte and L. J. Wittenberg, J. Metals 13, 692–693 (1961).
7.D. Turnbull, Trans. AIME 221, 422–439 (1961).
8.A. N. Campbell and S. Katz, J. Am. Chem. Soc. 57, 2051–2055 (1935).
9.It is of interest to point out that the specific heat of the solid phase does not enter into Eq. (4). A similar expression derived by Chalmers10 does involve the specific heat of the solid phase; however, we believe that if the temperature variation of the latent heat of fusion were properly taken into account, the dependence of on the solid‐phase specific heat would be removed from Chalmers’ expression.
10.B. Chalmers, Principles of Solidification (John Wiley & Sons, Inc., New York, 1964), p. 104.
11.This value based on constants listed in Ref. 12.
12.K. K. Kelley, USDI Bull. 476 (1949).
13.J. H. Hildebrand and G. J. Rotariu, J. Am. Chem. Soc. 73, 2524–2525 (1951).
14.J. R. van Wazer, Phosphorus and its Compounds (Interscience Publishers, Inc., New York, 1959).
15.H. Kramer and K. Schmeiser, Z. Physik. Chem. (Frankfurt) 35, 1–9 (1962).
16.F. E. Young and J. H. Hildebrand, J. Am. Chem. Soc. 64, 839–840 (1942).
17.The term stable denotes only relative stability between the liquid white phosphorus above and below 44 °C and not the absolute stability between the various polymorphic forms. Strictly speaking, white phosphorus at normal temperatures and pressure is unstable relative to the red modification.
18.S. Dobinski, Bull. Intern. Acad. Polon. Sci. Classe Sci. Math. Nat. Ser. A, 103 (1934–1939).
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