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Potential Field and Molecular Vibrations of the Trigonal Bipyramidal Model AX3YZ: Pentacoordinated Molecules. X
1.R. R. Holmes, R. P. Carter, Jr., and G. E. Peterson, Inorg. Chem. 3, 1748 (1964).
2.R. R. Holmes, J. Chem. Phys. 46, 3718 (1967).
3.J. E. Griffiths, R. P. Carter, Jr., and R. R. Holmes, J. Chem. Phys. 41, 863 (1964).
4.A. J. Downs and R. Schmutzler, Spectrochim. Acta 21, 1927 (1965).
5.(a) J. E. Griffiths, J. Chem. Phys. 41, 3510 (1964);
5.(b) J. E. Griffiths, 44, 2686 (1966)., J. Chem. Phys.
6.(a) A. Maccoll, Proc. Roy. Soc. (New South Wales) 69, 133 (1946);
6.(b) H. Siebert, Z. Anorg. Allgem. Chem. 265, 303 (1951);
6.(c) J. S. Ziomek and C. B. Mast, J. Chem. Phys. 21, 862 (1953);
6.(d) P. C. Haarhoff and C. W. F. T. Pistorius, Z. Naturforsch. 14a, 972 (1959). The development in (a) and (b) above agree with each other and have been reproduced by the present author, while Ref. (d) contains several errors in G matrix expressions.
7.The conditions on the redundant coordinates were obtained by examining the G matrix elements associated with the symmetry coordinates and (all of species). See E. B. Wilson, Jr., J. C. Decius, and P. C. Cross, Molecular Vibrations (McGraw‐Hill Book Co., New York, 1955), pp. 140–145.
8.The off‐diagonal element included in the calculations, is a function of D‐β interactions. However, excluded from the calculations, is also a function of D‐β interactions. Hence, D‐β interactions are partly neglected.
9.A. A. Maryott, S. J. Kryder, and R. R. Holmes, J. Chem. Phys. 43, 2556 (1965).
10.R. R. Holmes and R. P. Carter, Jr., J. Chem. Phys. 43, 1645 (1965).
11.K. W. Hansen and L. S. Bartell, Inorg. Chem. 4, 1775 (1965).
12.O. L. Hersh, Dissertation Abstr. 24, 2286 (1963).
13.M. Rouault, Ann. Phys. (Paris) 14, 78 (1940).
14.H. J. M. Bowen, Trans. Faraday Soc. 50, 463 (1954).
15.If the value of 1.780 Å, that was recently reported for the P‐C distance in by L. W. Bartell and K. W. Hansen [Inorg. Chem. 4, 1777 (1965)] is used, the symmetry force constants remain the same to three significant figures except for and which decrease by 8.3% and 3.0%, respectively.
16.(a) M. Radhakrishnan, Indian J. Pure Appl. Phys. 1, 437 (1963);
16.(b) G. Nagarajan, Indian J. Pure Appl. Phys. 2, 278 (1964), and references cited therein., Indian J. Pure Appl. Phys.
17.P. C. Van Der Voorn, K. F. Purcell, and R. S. Drago, J. Chem. Phys. 43, 3457 (1965). The latter authors obtain different values of symmetry force constants (their Table IV) when varying the order of frequencies in the same symmetry class thus establishing the calculations as erroneous and not as a “method” of assigning frequencies.
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