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Optical Transitions in 13CC5H6–C6H6 Mixed Crystals in the Region of the Factor‐Group Components of Crystalline Benzene
1.S. D. Colson, D. M. Hanson, R. Kopelman, and G. W. Robinson, J. Chem. Phys. 48, 2215 (1968).
2.E. R. Bernstein, S. D. Colson, D. S. Tinti, and G. W. Robinson, J. Chem. Phys. 48, 4632 (1968). This paper also shows that in a host the 0, 0 transition in is shifted by relative to the transition.
3.Although transitions to only three Davydov components are expected for benzene, absorption lines at 37 799, 37 803, 37 839, 37 846, and have been reported by V. L. Broude, V. S. Medvedev, and A. F. Prikhot’ko, Opt. Spektrosk. 2, 317 (1957)
3.and V. L. Broude, Sov. Phys.‐Usp. 4, 584 (1962).
4.Mixed‐crystal systems have been classified according to the magnitude of the local perturbation as very shallow guests, shallow guests, and deep guests. Because the exciton band is narrow and the deuterium isotope effect is large, even a single hydrogen‐deuterium substitution represents a shallow guest and leads to a bound exciton state in benzene. D. M. Hanson, R. Kopelman, and G. W. Robinson, J. Chem. Phys. 51, 212 (1969).
5.B. Sommer and J. Jortner, J. Chem. Phys. 50, 822 (1969).
6.Concentrations of and can be estimated by assuming the following probabilities for the crystal containing 50% and based on the 1% natural abundance of
7.D. P. Craig and M. R. Philpott, Proc. Roy. Soc. (London) A290, 583 (1966).
8.D. M. Hanson (unpublished results).
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